百科

(4S,6S)-4-{[(4R,4R)-4-(dimethylphenylsilyl)-6-oxo-3,4,5,6-tetrahydro-2H-pyran-2-yl]methyl}-6-(iodomethyl)-1,3-dioxan-2-one

(4S,6S)-4-{[(4R,4R)-4-(dimethylphenylsilyl)-6-oxo-3,4,5,6-tetrahydro-2H-pyran-2-yl]methyl}-6-(iodomethyl)-1,3-dioxan-2-one

CAS号：1643685-77-1

英文名：(4S,6S)-4-{[(4R,4R)-4-(dimethylphenylsilyl)-6-oxo-3,4,5,6-tetrahydro-2H-pyran-2-yl]methyl}-6-(iodomethyl)-1,3-dioxan-2-one

分子式：C19H25IO5Si

分子量：488.389

合成路线

(2S,4S)-1,5-dichloro-2,4-pentanediol

(2S,4S)-1,5-dichloro-2,4-pentanediol

(4S,6S)-4-{[(4R,4R)-4-(dimethylphenylsilyl)-6-oxo-3,4,5,6-tetrahydro-2H-pyran-2-yl]methyl}-6-(iodomethyl)-1,3-dioxan-2-one

(4S,6S)-4-{[(4R,4R)-4-(dimethylphenylsilyl)-6-oxo-3,4,5,6-tetrahydro-2H-pyran-2-yl]methyl}-6-(iodomethyl)-1,3-dioxan-2-one

上游原料

(2S,4S)-1,5-dichloro-2,4-pentanediol

下游产品

(S)-1-{(3R,4R,6R)-4-(dimethylphenylsilyl)-6-{[(4S,6S)-2,2-dimethyl-6-(phenylsulfanylmethyl)-1,3-dioxan-4-yl]methyl}-2-methoxy-3,4,5,6-tetrahydro-2H-pyran-3-yl}hexan-1-ol