百科

(+)-(4R,15R,16R,19R,20R,23R,24S)-16,19:20,23-Diepoxy-1,4,15,24-tetrahydroxy-4,15,24-O-tris(methoxymethyl)tetratriacontanoic acid methyl ester

(+)-(4R,15R,16R,19R,20R,23R,24S)-16,19:20,23-Diepoxy-1,4,15,24-tetrahydroxy-4,15,24-O-tris(methoxymethyl)tetratriacontanoic acid methyl ester

CAS号：165961-11-5

英文名：(+)-(4R,15R,16R,19R,20R,23R,24S)-16,19:20,23-Diepoxy-1,4,15,24-tetrahydroxy-4,15,24-O-tris(methoxymethyl)tetratriacontanoic acid methyl ester

分子式：C41H78O10

分子量：731.052

合成路线

(-)-(2S,3S,6R,7R,10S,11S)-2,3:10,11-Diepoxy-6,7-O-isopropylidene-1,12-O-bis(4-nitrobenzoyl)-1,6,7,12-tetrahydroxydodecane

(-)-(2S,3S,6R,7R,10S,11S)-2,3:10,11-Diepoxy-6,7-O-isopropylidene-1,12-O-bis(4-nitrobenzoyl)-1,6,7,12-tetrahydroxydodecane

(+)-(4R,15R,16R,19R,20R,23R,24S)-16,19:20,23-Diepoxy-1,4,15,24-tetrahydroxy-4,15,24-O-tris(methoxymethyl)tetratriacontanoic acid methyl ester

(+)-(4R,15R,16R,19R,20R,23R,24S)-16,19:20,23-Diepoxy-1,4,15,24-tetrahydroxy-4,15,24-O-tris(methoxymethyl)tetratriacontanoic acid methyl ester

(4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecan-1-ol

(4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecan-1-ol

(+)-(4R,15R,16R,19R,20R,23R,24S)-16,19:20,23-Diepoxy-1,4,15,24-tetrahydroxy-4,15,24-O-tris(methoxymethyl)tetratriacontanoic acid methyl ester

(+)-(4R,15R,16R,19R,20R,23R,24S)-16,19:20,23-Diepoxy-1,4,15,24-tetrahydroxy-4,15,24-O-tris(methoxymethyl)tetratriacontanoic acid methyl ester

(+)-(4R)-13-(Benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-4-<(methoxymethyl)oxy>tridecane

(+)-(4R)-13-(Benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-4-<(methoxymethyl)oxy>tridecane

(+)-(4R,15R,16R,19R,20R,23R,24S)-16,19:20,23-Diepoxy-1,4,15,24-tetrahydroxy-4,15,24-O-tris(methoxymethyl)tetratriacontanoic acid methyl ester

(+)-(4R,15R,16R,19R,20R,23R,24S)-16,19:20,23-Diepoxy-1,4,15,24-tetrahydroxy-4,15,24-O-tris(methoxymethyl)tetratriacontanoic acid methyl ester

(+)-(4R,15R,16R,19R,20R,23R,24S)-1-O-(tert-Butyldimethylsilyl)-4-O-(methoxymethyl)-16,19:20,23:24,25-triepoxy-1,4,15-trihydroxypentacosane

(+)-(4R,15R,16R,19R,20R,23R,24S)-1-O-(tert-Butyldimethylsilyl)-4-O-(methoxymethyl)-16,19:20,23:24,25-triepoxy-1,4,15-trihydroxypentacosane

(+)-(4R,15R,16R,19R,20R,23R,24S)-16,19:20,23-Diepoxy-1,4,15,24-tetrahydroxy-4,15,24-O-tris(methoxymethyl)tetratriacontanoic acid methyl ester

(+)-(4R,15R,16R,19R,20R,23R,24S)-16,19:20,23-Diepoxy-1,4,15,24-tetrahydroxy-4,15,24-O-tris(methoxymethyl)tetratriacontanoic acid methyl ester

((R)-10-Methoxymethoxy-tridec-12-enyloxymethyl)-benzene

((R)-10-Methoxymethoxy-tridec-12-enyloxymethyl)-benzene

(+)-(4R,15R,16R,19R,20R,23R,24S)-16,19:20,23-Diepoxy-1,4,15,24-tetrahydroxy-4,15,24-O-tris(methoxymethyl)tetratriacontanoic acid methyl ester

(+)-(4R,15R,16R,19R,20R,23R,24S)-16,19:20,23-Diepoxy-1,4,15,24-tetrahydroxy-4,15,24-O-tris(methoxymethyl)tetratriacontanoic acid methyl ester

(R)-13-(tert-Butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecan-1-ol

(R)-13-(tert-Butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecan-1-ol

(+)-(4R,15R,16R,19R,20R,23R,24S)-16,19:20,23-Diepoxy-1,4,15,24-tetrahydroxy-4,15,24-O-tris(methoxymethyl)tetratriacontanoic acid methyl ester

(+)-(4R,15R,16R,19R,20R,23R,24S)-16,19:20,23-Diepoxy-1,4,15,24-tetrahydroxy-4,15,24-O-tris(methoxymethyl)tetratriacontanoic acid methyl ester

上游原料

(+)-(4R)-13-(Benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-4-<(methoxymethyl)oxy>tridecane (-)-(2S,3S,6R,7R,10S,11S)-2,3:10,11-Diepoxy-6,7-O-isopropylidene-1,12-O-bis(4-nitrobenzoyl)-1,6,7,12-tetrahydroxydodecane (+)-(4R,15R,16R,19R,20R,23R,24S)-1-O-(tert-Butyldimethylsilyl)-4-O-(methoxymethyl)-16,19:20,23:24,25-triepoxy-1,4,15-trihydroxypentacosane (4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecan-1-ol (R)-13-(tert-Butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecan-1-ol ((R)-10-Methoxymethoxy-tridec-12-enyloxymethyl)-benzene

下游产品

(S)-3-{(2R,13R)-2,13-Bis-methoxymethoxy-13-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-tridecyl}-4-hydroxy-5-methyl-dihydro-furan-2-one