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(4R,5S)-3-{(E)-3-[(1R,3R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexyl]-acryloyl}-4-methyl-5-phenyl-oxazolidin-2-one

(4R,5S)-3-{(E)-3-[(1R,3R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexyl]-acryloyl}-4-methyl-5-phenyl-oxazolidin-2-one

CAS号：168777-85-3

英文名：(4R,5S)-3-{(E)-3-[(1R,3R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexyl]-acryloyl}-4-methyl-5-phenyl-oxazolidin-2-one

分子式：C26H39NO5Si

分子量：473.677

合成路线

((1S,2R,6R)-2-Benzyloxy-6-methoxy-cyclohexyloxy)-tert-butyl-dimethyl-silane

((1S,2R,6R)-2-Benzyloxy-6-methoxy-cyclohexyloxy)-tert-butyl-dimethyl-silane

(4R,5S)-3-{(E)-3-[(1R,3R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexyl]-acryloyl}-4-methyl-5-phenyl-oxazolidin-2-one

(4R,5S)-3-{(E)-3-[(1R,3R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexyl]-acryloyl}-4-methyl-5-phenyl-oxazolidin-2-one

(1R,2R,3R)-2-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexanol

(1R,2R,3R)-2-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexanol

(4R,5S)-3-{(E)-3-[(1R,3R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexyl]-acryloyl}-4-methyl-5-phenyl-oxazolidin-2-one

(4R,5S)-3-{(E)-3-[(1R,3R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexyl]-acryloyl}-4-methyl-5-phenyl-oxazolidin-2-one

(5R,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-cyclohex-2-enone

(5R,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-cyclohex-2-enone

(4R,5S)-3-{(E)-3-[(1R,3R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexyl]-acryloyl}-4-methyl-5-phenyl-oxazolidin-2-one

(4R,5S)-3-{(E)-3-[(1R,3R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexyl]-acryloyl}-4-methyl-5-phenyl-oxazolidin-2-one

(2S,3R)-2-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexanone

(2S,3R)-2-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexanone

(4R,5S)-3-{(E)-3-[(1R,3R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexyl]-acryloyl}-4-methyl-5-phenyl-oxazolidin-2-one

(4R,5S)-3-{(E)-3-[(1R,3R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexyl]-acryloyl}-4-methyl-5-phenyl-oxazolidin-2-one

上游原料

((1S,2R,6R)-2-Benzyloxy-6-methoxy-cyclohexyloxy)-tert-butyl-dimethyl-silane (2S,3R)-2-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexanone (1R,2R,3R)-2-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexanol (5R,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-cyclohex-2-enone

下游产品

(E)-(2R,3S,5S,6R,9R,10S,11R,12R,14S)-1-[(1S,3R,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methoxy-cyclohexyl]-10-methoxy-5,11-bis-(4-methoxy-benzyloxy)-2,6,8,12,14-pentamethyl-9-triisopropylsilanyloxy-hexadeca-7,15-dien-3-ol (E)-(2S,3S,5S,6R,9R,10S,11R,12R,14S)-2-[(1S,3R,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methoxy-cyclohexylmethyl]-10-methoxy-5,11-bis-(4-methoxy-benzyloxy)-6,8,12,14-tetramethyl-9-triisopropylsilanyloxy-hexadeca-7,15-diene-1,3-diol