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(E)-(S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-5-((R)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol

(E)-(S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-5-((R)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol

CAS号：169392-09-0

英文名：(E)-(S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-5-((R)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol

分子式：C19H38O4Si

分子量：358.588

合成路线

2-[(4R,6S)-6-((R)-1-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-propan-2-ol

2-[(4R,6S)-6-((R)-1-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-propan-2-ol

(E)-(S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-5-((R)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol

(E)-(S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-5-((R)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol

[(2R)-2-[(3aR,5S,6aR)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d] [1,3]dioxol-5-yl]-2-hydroxy-ethyl]4-methylbenzenesulfonate

[(2R)-2-[(3aR,5S,6aR)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d] [1,3]dioxol-5-yl]-2-hydroxy-ethyl]4-methylbenzenesulfonate

(E)-(S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-5-((R)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol

(E)-(S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-5-((R)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol

(4S,6R)-4-((R)-1-Benzyloxy-ethyl)-6-(bis-ethylsulfanyl-methyl)-2,2-dimethyl-[1,3]dioxane

(4S,6R)-4-((R)-1-Benzyloxy-ethyl)-6-(bis-ethylsulfanyl-methyl)-2,2-dimethyl-[1,3]dioxane

(E)-(S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-5-((R)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol

(E)-(S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-5-((R)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol

上游原料

(4S,6R)-4-((R)-1-Benzyloxy-ethyl)-6-(bis-ethylsulfanyl-methyl)-2,2-dimethyl-[1,3]dioxane 2-[(4R,6S)-6-((R)-1-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-propan-2-ol [(2R)-2-[(3aR,5S,6aR)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d] [1,3]dioxol-5-yl]-2-hydroxy-ethyl]4-methylbenzenesulfonate

下游产品

7-[(E)-(S)-4-Hydroxy-3-methyl-5-((R)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-pent-2-enyloxy]-chromen-2-one