百科

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

CAS号：170081-10-4

英文名：methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

分子式：C21H34O3

分子量：334.493

合成路线

(2R,2'R,4'aR,5R,8'aR)-decahydro-2'-hydroxy-2',5,5',5',8'a-pentamethylspiro(furan-2(3H),1'(2'H)-naphthalene)-5-acetaldehyde

(2R,2'R,4'aR,5R,8'aR)-decahydro-2'-hydroxy-2',5,5',5',8'a-pentamethylspiro(furan-2(3H),1'(2'H)-naphthalene)-5-acetaldehyde

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

(3aR,7aR)-4,4,7a-Trimethyl-1-oxo-octahydro-indene-2-carboxylic acid methyl ester

(3aR,7aR)-4,4,7a-Trimethyl-1-oxo-octahydro-indene-2-carboxylic acid methyl ester

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

(2R,2'R,4'aR,5R,8'aR)-decahydro-2',5,5',5',8'a-pentamethyl-5-vinylspiro<furan-2(3H),1'(2'H)-naphthalen>-2'-ol

(2R,2'R,4'aR,5R,8'aR)-decahydro-2',5,5',5',8'a-pentamethyl-5-vinylspiro<furan-2(3H),1'(2'H)-naphthalen>-2'-ol

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

(1R,2R)-2-(2-Carboxy-ethyl)-1,3,3-trimethyl-cyclohexanecarboxylic acid methyl ester

(1R,2R)-2-(2-Carboxy-ethyl)-1,3,3-trimethyl-cyclohexanecarboxylic acid methyl ester

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

(R)-2,3-Dihydro-2-methyl-2-vinylfuran

(R)-2,3-Dihydro-2-methyl-2-vinylfuran

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

(3aR,7aR)-hexahydro-4,4,7a-trimethyl-1-indanone

(3aR,7aR)-hexahydro-4,4,7a-trimethyl-1-indanone

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

(1R,2R)-2-carboxy-2,6,6-trimethylcyclohexanepropionic acid dimethyl ester

(1R,2R)-2-carboxy-2,6,6-trimethylcyclohexanepropionic acid dimethyl ester

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

(1R,3aR,7aR)-4,4,7a-Trimethyl-1-((R)-5-methyl-5-vinyl-4,5-dihydro-furan-2-yl)-octahydro-inden-1-ol

(1R,3aR,7aR)-4,4,7a-Trimethyl-1-((R)-5-methyl-5-vinyl-4,5-dihydro-furan-2-yl)-octahydro-inden-1-ol

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

(2R,2'R,4'aR,5R,8'aR)-decahydro-2'-hydroxy-2',5,5',5',8'a-pentamethylspiro(furan-2(3H),1'(2'H)-naphthalene)-5-ethanol

(2R,2'R,4'aR,5R,8'aR)-decahydro-2'-hydroxy-2',5,5',5',8'a-pentamethylspiro(furan-2(3H),1'(2'H)-naphthalene)-5-ethanol

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

methyl (2S,4'aR,5R,8'aR)-4,4'a,5,5',6',7',8',8'a-octahydro-2',5,5',5',8'a-pentamethylspiro<furan-2(3H),1'(4'H)-naphthalene>-5-acetate

上游原料

(3aR,7aR)-4,4,7a-Trimethyl-1-oxo-octahydro-indene-2-carboxylic acid methyl ester (3aR,7aR)-hexahydro-4,4,7a-trimethyl-1-indanone (1R,3aR,7aR)-4,4,7a-Trimethyl-1-((R)-5-methyl-5-vinyl-4,5-dihydro-furan-2-yl)-octahydro-inden-1-ol (2R,2'R,4'aR,5R,8'aR)-decahydro-2'-hydroxy-2',5,5',5',8'a-pentamethylspiro(furan-2(3H),1'(2'H)-naphthalene)-5-acetaldehyde (2R,2'R,4'aR,5R,8'aR)-decahydro-2'-hydroxy-2',5,5',5',8'a-pentamethylspiro(furan-2(3H),1'(2'H)-naphthalene)-5-ethanol (R)-2,3-Dihydro-2-methyl-2-vinylfuran (1R,2R)-2-carboxy-2,6,6-trimethylcyclohexanepropionic acid dimethyl ester (1R,2R)-2-(2-Carboxy-ethyl)-1,3,3-trimethyl-cyclohexanecarboxylic acid methyl ester (2R,2'R,4'aR,5R,8'aR)-decahydro-2',5,5',5',8'a-pentamethyl-5-vinylspiro<furan-2(3H),1'(2'H)-naphthalen>-2'-ol

下游产品

methyl 2-((2R,4a'R,5R,8a'R)-2'-(bromomethyl)-5,5',5',8a'-tetramethyl-4,4a',5,5',6',7',8',8a'-octahydro-3H,4'H-spiro[furan-2,1'-naphthalen]-5-yl)acetate methyl 2-((2R,3'S,4a'R,5R,8a'R)-3'-bromo-5,5',5',8a'-tetramethyl-2'-methylenedecahydro-2'H,3H-spiro[furan-2,1'-naphthalen]-5-yl)acetate