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Methyl 3-O-(tert-butyldimethylsilyl)-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hexafuranuronate

Methyl 3-O-(tert-butyldimethylsilyl)-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hexafuranuronate

CAS号：170873-00-4

英文名：Methyl 3-O-(tert-butyldimethylsilyl)-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hexafuranuronate

分子式：C16H30O6Si

分子量：346.491

合成路线

(+)-1,2-O-Isopropylidene-5-O-(phenoxythiocarbonyl)-α-D-glucurono-6,3-lactone

(+)-1,2-O-Isopropylidene-5-O-(phenoxythiocarbonyl)-α-D-glucurono-6,3-lactone

Methyl 3-O-(tert-butyldimethylsilyl)-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hexafuranuronate

Methyl 3-O-(tert-butyldimethylsilyl)-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hexafuranuronate

Methyl 1,2-O-isopropylidene-5-O-(phenoxythiocarbonyl)-α-D-glucuronate

Methyl 1,2-O-isopropylidene-5-O-(phenoxythiocarbonyl)-α-D-glucuronate

Methyl 3-O-(tert-butyldimethylsilyl)-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hexafuranuronate

Methyl 3-O-(tert-butyldimethylsilyl)-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hexafuranuronate

1,2-O-isopropylidene-β-D-idurono-3,6-lactone

1,2-O-isopropylidene-β-D-idurono-3,6-lactone

Methyl 3-O-(tert-butyldimethylsilyl)-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hexafuranuronate

Methyl 3-O-(tert-butyldimethylsilyl)-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hexafuranuronate

上游原料

(+)-1,2-O-Isopropylidene-5-O-(phenoxythiocarbonyl)-α-D-glucurono-6,3-lactone 1,2-O-isopropylidene-β-D-idurono-3,6-lactone Methyl 1,2-O-isopropylidene-5-O-(phenoxythiocarbonyl)-α-D-glucuronate

下游产品

(6R)-3-O-(tert-Butyldimethylsilyl)-6-C-<(1'R,3'S,4'R,5'S,6'S)-6'-endo-chloro-5'-endo-(methoxymethoxy)-2'-oxo-7'-oxabicyclo<2.2.1>hept-3'-exo-yl>-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hexofuranose 3-O-(tert-Butyldimethylsilyl)-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hexodialdo-1,4-furanose