[(1R,5R,6R)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-1-hydroxy-5-isopropenyl-2-methyl-cyclohex-2-enyl]-acetonitrile

[(1R,5R,6R)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-1-hydroxy-5-isopropenyl-2-methyl-cyclohex-2-enyl]-acetonitrile

CAS号：172172-73-5

英文名：[(1R,5R,6R)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-1-hydroxy-5-isopropenyl-2-methyl-cyclohex-2-enyl]-acetonitrile

分子式：C19H33NO2Si

分子量：335.556

合成路线

lithioacetonitrile

lithioacetonitrile

(5R,6R)-6-[(1,1-dimethylethyl)dimethylsilyloxymethyl]-2-methyl-5-(1-methylethenyl)-2-cyclohexen-1-one

(5R,6R)-6-[(1,1-dimethylethyl)dimethylsilyloxymethyl]-2-methyl-5-(1-methylethenyl)-2-cyclohexen-1-one

[(1R,5R,6R)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-1-hydroxy-5-isopropenyl-2-methyl-cyclohex-2-enyl]-acetonitrile

[(1R,5R,6R)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-1-hydroxy-5-isopropenyl-2-methyl-cyclohex-2-enyl]-acetonitrile

上游原料

lithioacetonitrile (5R,6R)-6-[(1,1-dimethylethyl)dimethylsilyloxymethyl]-2-methyl-5-(1-methylethenyl)-2-cyclohexen-1-one

下游产品

(2aS,2a1R,3R,4aR,5S,8R,8aS,9R)-4a-hydroxy-2a1-methyl-9-(prop-1-en-2-yl)-2a,3-bis((trimethylsilyl)oxy)octahydro-1,7-dioxa-5,8-methanocyclopenta[cd]azulene-2,6-dione