百科

(2aS,3R,4aR,5S,6R,7R,7aS,7bR)-7-Acetoxy-4a-hydroxy-6-isopropenyl-7b-methyl-2-oxo-2a,3-bis-trimethylsilanyloxy-decahydro-indeno[7,1-bc]furan-5-carboxylic acid methyl ester

(2aS,3R,4aR,5S,6R,7R,7aS,7bR)-7-Acetoxy-4a-hydroxy-6-isopropenyl-7b-methyl-2-oxo-2a,3-bis-trimethylsilanyloxy-decahydro-indeno[7,1-bc]furan-5-carboxylic acid methyl ester

CAS号：172172-84-8

英文名：(2aS,3R,4aR,5S,6R,7R,7aS,7bR)-7-Acetoxy-4a-hydroxy-6-isopropenyl-7b-methyl-2-oxo-2a,3-bis-trimethylsilanyloxy-decahydro-indeno[7,1-bc]furan-5-carboxylic acid methyl ester

分子式：C24H40O9Si2

分子量：528.74

合成路线

8,9-dihydroxy-β-bromopicrotoxinic acid methyl ester

8,9-dihydroxy-β-bromopicrotoxinic acid methyl ester

(2aS,3R,4aR,5S,6R,7R,7aS,7bR)-7-Acetoxy-4a-hydroxy-6-isopropenyl-7b-methyl-2-oxo-2a,3-bis-trimethylsilanyloxy-decahydro-indeno[7,1-bc]furan-5-carboxylic acid methyl ester

(2aS,3R,4aR,5S,6R,7R,7aS,7bR)-7-Acetoxy-4a-hydroxy-6-isopropenyl-7b-methyl-2-oxo-2a,3-bis-trimethylsilanyloxy-decahydro-indeno[7,1-bc]furan-5-carboxylic acid methyl ester

(5R,6R)-6-[(1,1-dimethylethyl)dimethylsilyloxymethyl]-2-methyl-5-(1-methylethenyl)-2-cyclohexen-1-one

(5R,6R)-6-[(1,1-dimethylethyl)dimethylsilyloxymethyl]-2-methyl-5-(1-methylethenyl)-2-cyclohexen-1-one

(2aS,3R,4aR,5S,6R,7R,7aS,7bR)-7-Acetoxy-4a-hydroxy-6-isopropenyl-7b-methyl-2-oxo-2a,3-bis-trimethylsilanyloxy-decahydro-indeno[7,1-bc]furan-5-carboxylic acid methyl ester

(2aS,3R,4aR,5S,6R,7R,7aS,7bR)-7-Acetoxy-4a-hydroxy-6-isopropenyl-7b-methyl-2-oxo-2a,3-bis-trimethylsilanyloxy-decahydro-indeno[7,1-bc]furan-5-carboxylic acid methyl ester

上游原料

8,9-dihydroxy-β-bromopicrotoxinic acid methyl ester (5R,6R)-6-[(1,1-dimethylethyl)dimethylsilyloxymethyl]-2-methyl-5-(1-methylethenyl)-2-cyclohexen-1-one

下游产品

8,9-dihydroxypicrotoxinin (2aS,2a1R,3R,4aR,5S,8R,8aS,9R)-4a-hydroxy-2a1-methyl-9-(prop-1-en-2-yl)-2a,3-bis((trimethylsilyl)oxy)octahydro-1,7-dioxa-5,8-methanocyclopenta[cd]azulene-2,6-dione