百科

(2S,3R,4R,5R,6R,5'S,6'R,7'R,8'R)-(3'E)-9'-<3,4-Bis(benzyloxy)-5-ethyl-tetrahydro-2-methoxy-2H-pyran-6-yl>-6'-methoxy-8'-<(methoxymethyl)oxy>-5',7'-dimethyl-3'-nonen-2'-one

(2S,3R,4R,5R,6R,5'S,6'R,7'R,8'R)-(3'E)-9'-<3,4-Bis(benzyloxy)-5-ethyl-tetrahydro-2-methoxy-2H-pyran-6-yl>-6'-methoxy-8'-<(methoxymethyl)oxy>-5',7'-dimethyl-3'-nonen-2'-one

CAS号：172603-21-3

英文名：(2S,3R,4R,5R,6R,5'S,6'R,7'R,8'R)-(3'E)-9'-<3,4-Bis(benzyloxy)-5-ethyl-tetrahydro-2-methoxy-2H-pyran-6-yl>-6'-methoxy-8'-<(methoxymethyl)oxy>-5',7'-dimethyl-3'-nonen-2'-one

分子式：C36H52O8

分子量：612.793

合成路线

Methyl 2,3-di-O-benzyl-4-deoxy-4-C-ethyl-α-D-gulopyranoside

Methyl 2,3-di-O-benzyl-4-deoxy-4-C-ethyl-α-D-gulopyranoside

(2S,3R,4R,5R,6R,5'S,6'R,7'R,8'R)-(3'E)-9'-<3,4-Bis(benzyloxy)-5-ethyl-tetrahydro-2-methoxy-2H-pyran-6-yl>-6'-methoxy-8'-<(methoxymethyl)oxy>-5',7'-dimethyl-3'-nonen-2'-one

(2S,3R,4R,5R,6R,5'S,6'R,7'R,8'R)-(3'E)-9'-<3,4-Bis(benzyloxy)-5-ethyl-tetrahydro-2-methoxy-2H-pyran-6-yl>-6'-methoxy-8'-<(methoxymethyl)oxy>-5',7'-dimethyl-3'-nonen-2'-one

Methyl 3,4-anhydro-6-O-(tert-butyldiphenylsilyl)-2-O-(methanesulfonyl)-α-D-allopyranoside

Methyl 3,4-anhydro-6-O-(tert-butyldiphenylsilyl)-2-O-(methanesulfonyl)-α-D-allopyranoside

(2S,3R,4R,5R,6R,5'S,6'R,7'R,8'R)-(3'E)-9'-<3,4-Bis(benzyloxy)-5-ethyl-tetrahydro-2-methoxy-2H-pyran-6-yl>-6'-methoxy-8'-<(methoxymethyl)oxy>-5',7'-dimethyl-3'-nonen-2'-one

(2S,3R,4R,5R,6R,5'S,6'R,7'R,8'R)-(3'E)-9'-<3,4-Bis(benzyloxy)-5-ethyl-tetrahydro-2-methoxy-2H-pyran-6-yl>-6'-methoxy-8'-<(methoxymethyl)oxy>-5',7'-dimethyl-3'-nonen-2'-one

(2R,3R,4R)-5-<(tert-Butyldiphenylsilyl)oxy>-3-methoxy-2,4-dimethylpentyl p-toluenesulfonate

(2R,3R,4R)-5-<(tert-Butyldiphenylsilyl)oxy>-3-methoxy-2,4-dimethylpentyl p-toluenesulfonate

(2S,3R,4R,5R,6R,5'S,6'R,7'R,8'R)-(3'E)-9'-<3,4-Bis(benzyloxy)-5-ethyl-tetrahydro-2-methoxy-2H-pyran-6-yl>-6'-methoxy-8'-<(methoxymethyl)oxy>-5',7'-dimethyl-3'-nonen-2'-one

(2S,3R,4R,5R,6R,5'S,6'R,7'R,8'R)-(3'E)-9'-<3,4-Bis(benzyloxy)-5-ethyl-tetrahydro-2-methoxy-2H-pyran-6-yl>-6'-methoxy-8'-<(methoxymethyl)oxy>-5',7'-dimethyl-3'-nonen-2'-one

(2S,3R,4R,5R,6R,2'S,3'R,4'R,5'R)-6'-<3,4-Bis(benzyloxy)-5-ethyl-tetrahydro-2-methoxy-2H-pyran-6-yl>-3'-methoxy-5'-<(methoxymethyl)oxy>-2',4'-dimethyl-1'-hexanol

(2S,3R,4R,5R,6R,2'S,3'R,4'R,5'R)-6'-<3,4-Bis(benzyloxy)-5-ethyl-tetrahydro-2-methoxy-2H-pyran-6-yl>-3'-methoxy-5'-<(methoxymethyl)oxy>-2',4'-dimethyl-1'-hexanol

(2S,3R,4R,5R,6R,5'S,6'R,7'R,8'R)-(3'E)-9'-<3,4-Bis(benzyloxy)-5-ethyl-tetrahydro-2-methoxy-2H-pyran-6-yl>-6'-methoxy-8'-<(methoxymethyl)oxy>-5',7'-dimethyl-3'-nonen-2'-one

(2S,3R,4R,5R,6R,5'S,6'R,7'R,8'R)-(3'E)-9'-<3,4-Bis(benzyloxy)-5-ethyl-tetrahydro-2-methoxy-2H-pyran-6-yl>-6'-methoxy-8'-<(methoxymethyl)oxy>-5',7'-dimethyl-3'-nonen-2'-one

上游原料

Methyl 3,4-anhydro-6-O-(tert-butyldiphenylsilyl)-2-O-(methanesulfonyl)-α-D-allopyranoside (2R,3R,4R)-5-<(tert-Butyldiphenylsilyl)oxy>-3-methoxy-2,4-dimethylpentyl p-toluenesulfonate (2S,3R,4R,5R,6R,2'S,3'R,4'R,5'R)-6'-<3,4-Bis(benzyloxy)-5-ethyl-tetrahydro-2-methoxy-2H-pyran-6-yl>-3'-methoxy-5'-<(methoxymethyl)oxy>-2',4'-dimethyl-1'-hexanol Methyl 2,3-di-O-benzyl-4-deoxy-4-C-ethyl-α-D-gulopyranoside

下游产品

5-乙基-5,6-二氢-6-[(2R,3S,4R,5S,7E)-2-羟基-4-甲氧基-3,5-二甲基-7-壬烯-1-基]-,(5R,6R)-2H-吡喃-2-酮 (2S,3R,4R,5R,6R,5'S,6'R,7'R,8'R)-(2'E)-9'-<5-Ethyl-tetrahydro-3,4-bis(methanesulfonyloxy)-2-methoxy-2H-pyran-6-yl>-6'-methoxy-8'-<(methoxymethyl)oxy>-5',7'-dimethyl-2'-nonene