百科

Trifluoro-methanesulfonic acid (3aS,4S,6R,7S,7aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-4-methoxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester

Trifluoro-methanesulfonic acid (3aS,4S,6R,7S,7aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-4-methoxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester

CAS号：172688-51-6

英文名：Trifluoro-methanesulfonic acid (3aS,4S,6R,7S,7aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-4-methoxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester

分子式：C27H35F3O8SSi

分子量：604.708

合成路线

methyl 6-O-(tert-butyldiphenylsilyl)-2,3-O-isopropylidene-4-oxo-α-D-lyxo-hexopyranoside

methyl 6-O-(tert-butyldiphenylsilyl)-2,3-O-isopropylidene-4-oxo-α-D-lyxo-hexopyranoside

Trifluoro-methanesulfonic acid (3aS,4S,6R,7S,7aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-4-methoxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester

Trifluoro-methanesulfonic acid (3aS,4S,6R,7S,7aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-4-methoxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester

methyl 6-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-α-D-mannopyranoside

methyl 6-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-α-D-mannopyranoside

Trifluoro-methanesulfonic acid (3aS,4S,6R,7S,7aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-4-methoxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester

Trifluoro-methanesulfonic acid (3aS,4S,6R,7S,7aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-4-methoxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester

上游原料

methyl 6-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-α-D-mannopyranoside methyl 6-O-(tert-butyldiphenylsilyl)-2,3-O-isopropylidene-4-oxo-α-D-lyxo-hexopyranoside

下游产品

4-azido-4-deoxy-2,3-O-isopropylidene-D-mannononitrile (5R,6S,7R)-5,6,7trihydro-5-(1R-1,2-dihydroxyethyl)-6,7-O-isopropylidenepyrrolo<1,2-d>tetrazole-6,7-diol 4-azido-4-deoxy-α-D-mannopyranose 4-azido-4-deoxy-2,3-O-isopropylidene-D-mannono-1,5-lactone 4-azido-4-deoxy-2,3-O-isopropylidene-α-D-mannose