百科

Toluene-4-sulfonic acid (1R,2R,3S,4R,4aR,11bS)-2,3-dihydroxy-4-(4-methoxy-benzyloxy)-2,3,4,4a,6,11b-hexahydro-1H-5,8,10-trioxa-cyclopenta[b]phenanthren-1-yl ester

Toluene-4-sulfonic acid (1R,2R,3S,4R,4aR,11bS)-2,3-dihydroxy-4-(4-methoxy-benzyloxy)-2,3,4,4a,6,11b-hexahydro-1H-5,8,10-trioxa-cyclopenta[b]phenanthren-1-yl ester

CAS号：173425-91-7

英文名：Toluene-4-sulfonic acid (1R,2R,3S,4R,4aR,11bS)-2,3-dihydroxy-4-(4-methoxy-benzyloxy)-2,3,4,4a,6,11b-hexahydro-1H-5,8,10-trioxa-cyclopenta[b]phenanthren-1-yl ester

分子式：C29H30O10S

分子量：570.607

合成路线

(3a'R,4'S,4a'S,7a'R,8'S,8a'R)-4'-((4-methoxybenzyl)oxy)hexahydrodispiro[cyclohexane-1,2'-benzo[1,2-d:4,5-d']bis([1,3]dioxole)-6',1''-cyclohexan]-8'-yl 4-methylbenzenesulfonate

(3a'R,4'S,4a'S,7a'R,8'S,8a'R)-4'-((4-methoxybenzyl)oxy)hexahydrodispiro[cyclohexane-1,2'-benzo[1,2-d:4,5-d']bis([1,3]dioxole)-6',1''-cyclohexan]-8'-yl 4-methylbenzenesulfonate

Toluene-4-sulfonic acid (1R,2R,3S,4R,4aR,11bS)-2,3-dihydroxy-4-(4-methoxy-benzyloxy)-2,3,4,4a,6,11b-hexahydro-1H-5,8,10-trioxa-cyclopenta[b]phenanthren-1-yl ester

Toluene-4-sulfonic acid (1R,2R,3S,4R,4aR,11bS)-2,3-dihydroxy-4-(4-methoxy-benzyloxy)-2,3,4,4a,6,11b-hexahydro-1H-5,8,10-trioxa-cyclopenta[b]phenanthren-1-yl ester

(3a'R,4'S,4a'R,11b'S,12'R,12a'R)-4'-((4-methoxybenzyl)oxy)-3a',4',4a',11b',12',12a'-hexahydro-6'H-spiro[cyclohexane-1,2'-[1,3]dioxolo[4',5':4,5]benzo[1,2-c][1,3]dioxolo[4,5-g]chromen]-12'-yl 4-methylbenzenesulfonate

(3a'R,4'S,4a'R,11b'S,12'R,12a'R)-4'-((4-methoxybenzyl)oxy)-3a',4',4a',11b',12',12a'-hexahydro-6'H-spiro[cyclohexane-1,2'-[1,3]dioxolo[4',5':4,5]benzo[1,2-c][1,3]dioxolo[4,5-g]chromen]-12'-yl 4-methylbenzenesulfonate

Toluene-4-sulfonic acid (1R,2R,3S,4R,4aR,11bS)-2,3-dihydroxy-4-(4-methoxy-benzyloxy)-2,3,4,4a,6,11b-hexahydro-1H-5,8,10-trioxa-cyclopenta[b]phenanthren-1-yl ester

Toluene-4-sulfonic acid (1R,2R,3S,4R,4aR,11bS)-2,3-dihydroxy-4-(4-methoxy-benzyloxy)-2,3,4,4a,6,11b-hexahydro-1H-5,8,10-trioxa-cyclopenta[b]phenanthren-1-yl ester

上游原料

(3a'R,4'S,4a'R,11b'S,12'R,12a'R)-4'-((4-methoxybenzyl)oxy)-3a',4',4a',11b',12',12a'-hexahydro-6'H-spiro[cyclohexane-1,2'-[1,3]dioxolo[4',5':4,5]benzo[1,2-c][1,3]dioxolo[4,5-g]chromen]-12'-yl 4-methylbenzenesulfonate (3a'R,4'S,4a'S,7a'R,8'S,8a'R)-4'-((4-methoxybenzyl)oxy)hexahydrodispiro[cyclohexane-1,2'-benzo[1,2-d:4,5-d']bis([1,3]dioxole)-6',1''-cyclohexan]-8'-yl 4-methylbenzenesulfonate

下游产品

(1R,2S,3S,4R,4aR,11bR)-1-Azido-4-(4-methoxy-benzyloxy)-2,3,4,4a,6,11b-hexahydro-1H-5,8,10-trioxa-cyclopenta[b]phenanthrene-2,3-diol