百科

(R)-1-[(2R,5R,2'R,5'R)-5'-((R)-1-Hydroxy-but-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol

(R)-1-[(2R,5R,2'R,5'R)-5'-((R)-1-Hydroxy-but-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol

CAS号：173427-96-8

英文名：(R)-1-[(2R,5R,2'R,5'R)-5'-((R)-1-Hydroxy-but-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol

分子式：C23H36O4

分子量：376.53

合成路线

Toluene-4-sulfonic acid (S)-2-(tert-butyl-dimethyl-silanyloxy)-1-{(2R,5R,2'R,5'R)-5'-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-hydroxy-ethyl]-octahydro-[2,2']bifuranyl-5-yl}-ethyl ester

Toluene-4-sulfonic acid (S)-2-(tert-butyl-dimethyl-silanyloxy)-1-{(2R,5R,2'R,5'R)-5'-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-hydroxy-ethyl]-octahydro-[2,2']bifuranyl-5-yl}-ethyl ester

(R)-1-[(2R,5R,2'R,5'R)-5'-((R)-1-Hydroxy-but-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol

(R)-1-[(2R,5R,2'R,5'R)-5'-((R)-1-Hydroxy-but-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol

Acetic acid (S)-2-[(2R,5R,2'R,5'R)-5'-((R)-1-acetoxy-undec-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-2-(toluene-4-sulfonyloxy)-ethyl ester

Acetic acid (S)-2-[(2R,5R,2'R,5'R)-5'-((R)-1-acetoxy-undec-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-2-(toluene-4-sulfonyloxy)-ethyl ester

(R)-1-[(2R,5R,2'R,5'R)-5'-((R)-1-Hydroxy-but-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol

(R)-1-[(2R,5R,2'R,5'R)-5'-((R)-1-Hydroxy-but-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol

(-)-(2R,3R,6R,7R,10R,11R)-1,2:3,6:7,10:11,12-tetraepoxydodecane

(-)-(2R,3R,6R,7R,10R,11R)-1,2:3,6:7,10:11,12-tetraepoxydodecane

(R)-1-[(2R,5R,2'R,5'R)-5'-((R)-1-Hydroxy-but-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol

(R)-1-[(2R,5R,2'R,5'R)-5'-((R)-1-Hydroxy-but-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol

Acetic acid (R)-1-[(2R,5R,2'R,5'R)-5'-((S)-2-acetoxy-1-methoxymethoxy-ethyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-ynyl ester

Acetic acid (R)-1-[(2R,5R,2'R,5'R)-5'-((S)-2-acetoxy-1-methoxymethoxy-ethyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-ynyl ester

(R)-1-[(2R,5R,2'R,5'R)-5'-((R)-1-Hydroxy-but-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol

(R)-1-[(2R,5R,2'R,5'R)-5'-((R)-1-Hydroxy-but-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol

(R)-1-[(2R,5R,2'R,5'R)-5'-((S)-2-Hydroxy-1-methoxymethoxy-ethyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol

(R)-1-[(2R,5R,2'R,5'R)-5'-((S)-2-Hydroxy-1-methoxymethoxy-ethyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol

(R)-1-[(2R,5R,2'R,5'R)-5'-((R)-1-Hydroxy-but-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol

(R)-1-[(2R,5R,2'R,5'R)-5'-((R)-1-Hydroxy-but-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol

(1S,1'S)-((2R,2'R,5R,5'R)-octahydro-[2,2'-bifuran]-5,5'-diyl)bis(2-((tert-butyldiphenylsilyl)oxy)ethane-1,1-diyl) bis(4-methylbenzenesulfonate)

(1S,1'S)-((2R,2'R,5R,5'R)-octahydro-[2,2'-bifuran]-5,5'-diyl)bis(2-((tert-butyldiphenylsilyl)oxy)ethane-1,1-diyl) bis(4-methylbenzenesulfonate)

(R)-1-[(2R,5R,2'R,5'R)-5'-((R)-1-Hydroxy-but-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol

(R)-1-[(2R,5R,2'R,5'R)-5'-((R)-1-Hydroxy-but-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol

上游原料

Acetic acid (R)-1-[(2R,5R,2'R,5'R)-5'-((S)-2-acetoxy-1-methoxymethoxy-ethyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-ynyl ester (1S,1'S)-((2R,2'R,5R,5'R)-octahydro-[2,2'-bifuran]-5,5'-diyl)bis(2-((tert-butyldiphenylsilyl)oxy)ethane-1,1-diyl) bis(4-methylbenzenesulfonate) Acetic acid (S)-2-[(2R,5R,2'R,5'R)-5'-((R)-1-acetoxy-undec-3-ynyl)-octahydro-[2,2']bifuranyl-5-yl]-2-(toluene-4-sulfonyloxy)-ethyl ester (R)-1-[(2R,5R,2'R,5'R)-5'-((S)-2-Hydroxy-1-methoxymethoxy-ethyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-3-yn-1-ol Toluene-4-sulfonic acid (S)-2-(tert-butyl-dimethyl-silanyloxy)-1-{(2R,5R,2'R,5'R)-5'-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-hydroxy-ethyl]-octahydro-[2,2']bifuranyl-5-yl}-ethyl ester (-)-(2R,3R,6R,7R,10R,11R)-1,2:3,6:7,10:11,12-tetraepoxydodecane

下游产品

{2R-[2α[2'R*, 5'R*(R*)],5β],[1(S*), 2R*, 11R*]}-3-{2-[(1,1-dimethylethyl)diphenylsilyloxy]-11-hydroxy-11-[octahydro-5'-(1-hydroxyundec-3-ynyl) [2.2'-bifuran]-5-yl]-6-undecen-8-ynyl}-5-methyl-2-(5H)-furanone