百科

(5S,6R)-5,6-二氢-5-羟基-6-甲基-3-[(2S,3S)-3-甲基环氧乙烷基]-2H-吡喃-2-酮

(5S,6R)-5,6-二氢-5-羟基-6-甲基-3-[(2S,3S)-3-甲基环氧乙烷基]-2H-吡喃-2-酮

CAS号：17398-00-4

英文名：(2R,3S)-3-hydroxy-2-methyl-5-[(2S,3S)-3-methyloxiran-2-yl]-2,3-dihydropyran-6-one

分子式：C9H12O4

分子量：184.189

合成路线

乙酸酐

(5S,6R,1'S, 2'S)-5-t-butyldimethylsiloxy-3-(1',2'-epoxypropyl)-6-methyl-5,6-dihydro-2H-pyran-2-one

(5S,6R,1'S, 2'S)-5-t-butyldimethylsiloxy-3-(1',2'-epoxypropyl)-6-methyl-5,6-dihydro-2H-pyran-2-one

(5S,6R)-5,6-二氢-5-羟基-6-甲基-3-[(2S,3S)-3-甲基环氧乙烷基]-2H-吡喃-2-酮

(5S,6R)-5,6-二氢-5-羟基-6-甲基-3-[(2S,3S)-3-甲基环氧乙烷基]-2H-吡喃-2-酮

(5S,6R,1'S, 2'S)-5-t-butyldimethylsiloxy-3-(1',2'-epoxypropyl)-6-methyl-5,6-dihydro-2H-pyran-2-one

(5S,6R,1'S, 2'S)-5-t-butyldimethylsiloxy-3-(1',2'-epoxypropyl)-6-methyl-5,6-dihydro-2H-pyran-2-one

(5S,6R)-5,6-二氢-5-羟基-6-甲基-3-[(2S,3S)-3-甲基环氧乙烷基]-2H-吡喃-2-酮

(5S,6R)-5,6-二氢-5-羟基-6-甲基-3-[(2S,3S)-3-甲基环氧乙烷基]-2H-吡喃-2-酮

(5S,6R)-5-t-butyldimethylsiloxy-6-methyl-3-phenylselenotetrahydro-2H-pyran-2-one

(5S,6R)-5-t-butyldimethylsiloxy-6-methyl-3-phenylselenotetrahydro-2H-pyran-2-one

(5S,6R)-5,6-二氢-5-羟基-6-甲基-3-[(2S,3S)-3-甲基环氧乙烷基]-2H-吡喃-2-酮

(5S,6R)-5,6-二氢-5-羟基-6-甲基-3-[(2S,3S)-3-甲基环氧乙烷基]-2H-吡喃-2-酮

(2R,3S)-6-(benzyloxy)-2-methyl-3,6-dihydro-2H-pyran-3-ol

(2R,3S)-6-(benzyloxy)-2-methyl-3,6-dihydro-2H-pyran-3-ol

(5S,6R)-5,6-二氢-5-羟基-6-甲基-3-[(2S,3S)-3-甲基环氧乙烷基]-2H-吡喃-2-酮

(5S,6R)-5,6-二氢-5-羟基-6-甲基-3-[(2S,3S)-3-甲基环氧乙烷基]-2H-吡喃-2-酮

benzyl 4-O-acetyl-2,3,6-trideoxy-D-erythro-hex-2-enopyranoside

benzyl 4-O-acetyl-2,3,6-trideoxy-D-erythro-hex-2-enopyranoside

(5S,6R)-5,6-二氢-5-羟基-6-甲基-3-[(2S,3S)-3-甲基环氧乙烷基]-2H-吡喃-2-酮

(5S,6R)-5,6-二氢-5-羟基-6-甲基-3-[(2S,3S)-3-甲基环氧乙烷基]-2H-吡喃-2-酮

phenylmethyl 2,3,6-trideoxy-4-O-((1,1-dimethylethyl)dimethylsilyl)-α-L-erythro-hex-2-enopyranoside

phenylmethyl 2,3,6-trideoxy-4-O-((1,1-dimethylethyl)dimethylsilyl)-α-L-erythro-hex-2-enopyranoside

(5S,6R)-5,6-二氢-5-羟基-6-甲基-3-[(2S,3S)-3-甲基环氧乙烷基]-2H-吡喃-2-酮

(5S,6R)-5,6-二氢-5-羟基-6-甲基-3-[(2S,3S)-3-甲基环氧乙烷基]-2H-吡喃-2-酮

3,4-di-O-acetyl-D-rhamnal

3,4-di-O-acetyl-D-rhamnal

(5S,6R)-5,6-二氢-5-羟基-6-甲基-3-[(2S,3S)-3-甲基环氧乙烷基]-2H-吡喃-2-酮

(5S,6R)-5,6-二氢-5-羟基-6-甲基-3-[(2S,3S)-3-甲基环氧乙烷基]-2H-吡喃-2-酮

上游原料

(5S,6R)-5-t-butyldimethylsiloxy-6-methyl-3-phenylselenotetrahydro-2H-pyran-2-one 乙酸酐 (5S,6R,1'S, 2'S)-5-t-butyldimethylsiloxy-3-(1',2'-epoxypropyl)-6-methyl-5,6-dihydro-2H-pyran-2-one benzyl 4-O-acetyl-2,3,6-trideoxy-D-erythro-hex-2-enopyranoside 3,4-di-O-acetyl-D-rhamnal phenylmethyl 2,3,6-trideoxy-4-O-((1,1-dimethylethyl)dimethylsilyl)-α-L-erythro-hex-2-enopyranoside (2R,3S)-6-(benzyloxy)-2-methyl-3,6-dihydro-2H-pyran-3-ol

下游产品

chlorohydroaspyrone Asperlactone; (5R)-5-[(1S)-1-羟基乙基]-3-[(2S,3S)-3-甲基-2-环氧乙烷基]-2(5H)-呋喃酮 chlorohydroaspyrone A