百科

(1R,2S,3S,4S,5R)-1-O-acetyl-2-O-benzyl-5-iodo-3,4-O-isopropylidenecyclopentane-1,2,3,4-tetrol

(1R,2S,3S,4S,5R)-1-O-acetyl-2-O-benzyl-5-iodo-3,4-O-isopropylidenecyclopentane-1,2,3,4-tetrol

CAS号：174149-76-9

英文名：(1R,2S,3S,4S,5R)-1-O-acetyl-2-O-benzyl-5-iodo-3,4-O-isopropylidenecyclopentane-1,2,3,4-tetrol

分子式：C17H21IO5

分子量：432.25

合成路线

(S)-4-叔丁基二甲基硅氧基-2-环戊酮

(S)-4-叔丁基二甲基硅氧基-2-环戊酮

(1R,2S,3S,4S,5R)-1-O-acetyl-2-O-benzyl-5-iodo-3,4-O-isopropylidenecyclopentane-1,2,3,4-tetrol

(1R,2S,3S,4S,5R)-1-O-acetyl-2-O-benzyl-5-iodo-3,4-O-isopropylidenecyclopentane-1,2,3,4-tetrol

(1R,4S)-1-O-benzyl-4-O-(tert-butyldimethylsilyl)cyclopent-2-ene-1,4-diol

(1R,4S)-1-O-benzyl-4-O-(tert-butyldimethylsilyl)cyclopent-2-ene-1,4-diol

(1R,2S,3S,4S,5R)-1-O-acetyl-2-O-benzyl-5-iodo-3,4-O-isopropylidenecyclopentane-1,2,3,4-tetrol

(1R,2S,3S,4S,5R)-1-O-acetyl-2-O-benzyl-5-iodo-3,4-O-isopropylidenecyclopentane-1,2,3,4-tetrol

(1R,2R,3S,4S)-1-O-benzyl-4-O-(tert-butyldimethylsilyl)cyclopentane-1,2,3,4-tetrol

(1R,2R,3S,4S)-1-O-benzyl-4-O-(tert-butyldimethylsilyl)cyclopentane-1,2,3,4-tetrol

(1R,2S,3S,4S,5R)-1-O-acetyl-2-O-benzyl-5-iodo-3,4-O-isopropylidenecyclopentane-1,2,3,4-tetrol

(1R,2S,3S,4S,5R)-1-O-acetyl-2-O-benzyl-5-iodo-3,4-O-isopropylidenecyclopentane-1,2,3,4-tetrol

(1R,2S,3S,4S)-1-O-benzyl-4-O-(tert-butyldimethylsilyl)-2,3-O-isopropylidenecyclopentane-1,2,3,4-tetrol

(1R,2S,3S,4S)-1-O-benzyl-4-O-(tert-butyldimethylsilyl)-2,3-O-isopropylidenecyclopentane-1,2,3,4-tetrol

(1R,2S,3S,4S,5R)-1-O-acetyl-2-O-benzyl-5-iodo-3,4-O-isopropylidenecyclopentane-1,2,3,4-tetrol

(1R,2S,3S,4S,5R)-1-O-acetyl-2-O-benzyl-5-iodo-3,4-O-isopropylidenecyclopentane-1,2,3,4-tetrol

上游原料

(S)-4-叔丁基二甲基硅氧基-2-环戊酮 (1R,4S)-1-O-benzyl-4-O-(tert-butyldimethylsilyl)cyclopent-2-ene-1,4-diol (1R,2R,3S,4S)-1-O-benzyl-4-O-(tert-butyldimethylsilyl)cyclopentane-1,2,3,4-tetrol (1R,2S,3S,4S)-1-O-benzyl-4-O-(tert-butyldimethylsilyl)-2,3-O-isopropylidenecyclopentane-1,2,3,4-tetrol

下游产品

(3aS,4R,5S,6R,6aS)-4,6-dihydroxy-5-(methylthio)cyclopent<d>oxazolidin-2-one (3aR,4R,5R,6R,7aS)-6-benzoxy-4,5-dihydroxycyclopent<d>oxazolidin-5-one (3aR,4S,5S,6S,6aS)-5,6-dihydroxy-4-(methylthio)cyclopent<d>oxazolidin-2-one (3aR,3bS,6aR,7R,7aR)-7-benzoxy-2,2-dimethyl<1,3>dioxolo<4,5-a>cyclopent<4,5-d>oxazolidin-5-one (1R,2S,3S,4S,5R)-2-O-benzyl-1-O-(tert-butyldimethylsilyl)-5-iodo-3,4-O-isopropylidenecyclopentane-1,2,3,4-tetrol (1S,2S,3R,4R,5S)-5-azido-2-O-benzyl-1-O-(tert-butyldimethylsilyl)-3,4-O-isopropylidenecyclopentane-1,2,3,4-tetrol (3aR,3bR,6aS,7R,7aS)-7-benzoxy<1,3,2>dioxathiolo<4,5-a>cyclopent<4,5-d>oxazolidin-2,2,5-trione (1S,2S,3R,4R,5R)-2-O-benzyl-5-((tert-butoxycarbonyl)amino)-3,4-O-isopropylidenecyclopentane-1,2,3,4-tetrol (1S,2S,3R,4R,5S)-2-O-benzyl-5-((tert-butoxycarbonyl)amino)-1-O-(tert-butyldimethylsilyl)-3,4-O-isopropylidenecyclopentane-1,2,3,4-tetrol