百科

Acetic acid (E)-(1S,4S,5S,8S,9S)-8-acetoxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-9-methoxymethoxy-1-((E)-(S)-1-methoxymethoxy-but-2-enyl)-dodec-10-enyl ester

Acetic acid (E)-(1S,4S,5S,8S,9S)-8-acetoxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-9-methoxymethoxy-1-((E)-(S)-1-methoxymethoxy-but-2-enyl)-dodec-10-enyl ester

CAS号：177854-15-8

英文名：Acetic acid (E)-(1S,4S,5S,8S,9S)-8-acetoxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-9-methoxymethoxy-1-((E)-(S)-1-methoxymethoxy-but-2-enyl)-dodec-10-enyl ester

分子式：C36H70O10Si2

分子量：719.106

合成路线

Diethyl (4S,5S)-4,5-bis(tert-butyldimethylsilyloxy)-(2E,6E)-octadienedioate

Diethyl (4S,5S)-4,5-bis(tert-butyldimethylsilyloxy)-(2E,6E)-octadienedioate

Acetic acid (E)-(1S,4S,5S,8S,9S)-8-acetoxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-9-methoxymethoxy-1-((E)-(S)-1-methoxymethoxy-but-2-enyl)-dodec-10-enyl ester

Acetic acid (E)-(1S,4S,5S,8S,9S)-8-acetoxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-9-methoxymethoxy-1-((E)-(S)-1-methoxymethoxy-but-2-enyl)-dodec-10-enyl ester

(4S,5S)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-octanedial

(4S,5S)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-octanedial

Acetic acid (E)-(1S,4S,5S,8S,9S)-8-acetoxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-9-methoxymethoxy-1-((E)-(S)-1-methoxymethoxy-but-2-enyl)-dodec-10-enyl ester

Acetic acid (E)-(1S,4S,5S,8S,9S)-8-acetoxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-9-methoxymethoxy-1-((E)-(S)-1-methoxymethoxy-but-2-enyl)-dodec-10-enyl ester

(4S,5S)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-octanedioic acid diethyl ester

(4S,5S)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-octanedioic acid diethyl ester

Acetic acid (E)-(1S,4S,5S,8S,9S)-8-acetoxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-9-methoxymethoxy-1-((E)-(S)-1-methoxymethoxy-but-2-enyl)-dodec-10-enyl ester

Acetic acid (E)-(1S,4S,5S,8S,9S)-8-acetoxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-9-methoxymethoxy-1-((E)-(S)-1-methoxymethoxy-but-2-enyl)-dodec-10-enyl ester

上游原料

(4S,5S)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-octanedioic acid diethyl ester (4S,5S)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-octanedial Diethyl (4S,5S)-4,5-bis(tert-butyldimethylsilyloxy)-(2E,6E)-octadienedioate

下游产品

Acetic acid (E)-(1S,4S,5S,8S,9S)-8-acetoxy-4,5-dihydroxy-9-methoxymethoxy-1-((E)-(S)-1-methoxymethoxy-but-2-enyl)-dodec-10-enyl ester (2R,5S,2'R,5'S)-5,5'-Bis-((E)-(S)-1-methoxymethoxy-but-2-enyl)-octahydro-[2,2']bifuranyl Acetic acid (E)-(1S,4S,5S,8S,9S)-8-acetoxy-4,5-bis-methanesulfonyloxy-9-methoxymethoxy-1-((E)-(S)-1-methoxymethoxy-but-2-enyl)-dodec-10-enyl ester