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(5S,6R,7R)-5-(2-(benzyloxy)ethyl)-3,3,9,9-tetraethyl-6-methyl-7-((R)-1-(phenylthio)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

(5S,6R,7R)-5-(2-(benzyloxy)ethyl)-3,3,9,9-tetraethyl-6-methyl-7-((R)-1-(phenylthio)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

CAS号：179945-14-3

英文名：(5S,6R,7R)-5-(2-(benzyloxy)ethyl)-3,3,9,9-tetraethyl-6-methyl-7-((R)-1-(phenylthio)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

分子式：C34H58O3SSi2

分子量：603.059

合成路线

(2R,3S)-5-Benzyloxy-2-methyl-3-triethylsilanyloxy-pentanal

(2R,3S)-5-Benzyloxy-2-methyl-3-triethylsilanyloxy-pentanal

(5S,6R,7R)-5-(2-(benzyloxy)ethyl)-3,3,9,9-tetraethyl-6-methyl-7-((R)-1-(phenylthio)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

(5S,6R,7R)-5-(2-(benzyloxy)ethyl)-3,3,9,9-tetraethyl-6-methyl-7-((R)-1-(phenylthio)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

(E)-(4S,5S)-7-Benzyloxy-4-methyl-5-triethylsilanyloxy-hept-2-en-1-ol

(E)-(4S,5S)-7-Benzyloxy-4-methyl-5-triethylsilanyloxy-hept-2-en-1-ol

(5S,6R,7R)-5-(2-(benzyloxy)ethyl)-3,3,9,9-tetraethyl-6-methyl-7-((R)-1-(phenylthio)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

(5S,6R,7R)-5-(2-(benzyloxy)ethyl)-3,3,9,9-tetraethyl-6-methyl-7-((R)-1-(phenylthio)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

(4R,5S)-3-((2R,3S)-5-Benzyloxy-3-hydroxy-2-methyl-pentanoyl)-4-methyl-5-phenyl-oxazolidin-2-one

(4R,5S)-3-((2R,3S)-5-Benzyloxy-3-hydroxy-2-methyl-pentanoyl)-4-methyl-5-phenyl-oxazolidin-2-one

(5S,6R,7R)-5-(2-(benzyloxy)ethyl)-3,3,9,9-tetraethyl-6-methyl-7-((R)-1-(phenylthio)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

(5S,6R,7R)-5-(2-(benzyloxy)ethyl)-3,3,9,9-tetraethyl-6-methyl-7-((R)-1-(phenylthio)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

(2R,3S)-5-Benzyloxy-2-methyl-3-triethylsilanyloxy-pentanoic acid methoxy-methyl-amide

(2R,3S)-5-Benzyloxy-2-methyl-3-triethylsilanyloxy-pentanoic acid methoxy-methyl-amide

(5S,6R,7R)-5-(2-(benzyloxy)ethyl)-3,3,9,9-tetraethyl-6-methyl-7-((R)-1-(phenylthio)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

(5S,6R,7R)-5-(2-(benzyloxy)ethyl)-3,3,9,9-tetraethyl-6-methyl-7-((R)-1-(phenylthio)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

[(2R,3R)-3-((1S,2S)-4-Benzyloxy-1-methyl-2-triethylsilanyloxy-butyl)-oxiranyl]-methanol

[(2R,3R)-3-((1S,2S)-4-Benzyloxy-1-methyl-2-triethylsilanyloxy-butyl)-oxiranyl]-methanol

(5S,6R,7R)-5-(2-(benzyloxy)ethyl)-3,3,9,9-tetraethyl-6-methyl-7-((R)-1-(phenylthio)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

(5S,6R,7R)-5-(2-(benzyloxy)ethyl)-3,3,9,9-tetraethyl-6-methyl-7-((R)-1-(phenylthio)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

(E)-(4S,5S)-7-Benzyloxy-4-methyl-5-triethylsilanyloxy-hept-2-enoic acid ethyl ester

(E)-(4S,5S)-7-Benzyloxy-4-methyl-5-triethylsilanyloxy-hept-2-enoic acid ethyl ester

(5S,6R,7R)-5-(2-(benzyloxy)ethyl)-3,3,9,9-tetraethyl-6-methyl-7-((R)-1-(phenylthio)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

(5S,6R,7R)-5-(2-(benzyloxy)ethyl)-3,3,9,9-tetraethyl-6-methyl-7-((R)-1-(phenylthio)propan-2-yl)-4,8-dioxa-3,9-disilaundecane

上游原料

(2R,3S)-5-Benzyloxy-2-methyl-3-triethylsilanyloxy-pentanal (E)-(4S,5S)-7-Benzyloxy-4-methyl-5-triethylsilanyloxy-hept-2-enoic acid ethyl ester (E)-(4S,5S)-7-Benzyloxy-4-methyl-5-triethylsilanyloxy-hept-2-en-1-ol (4R,5S)-3-((2R,3S)-5-Benzyloxy-3-hydroxy-2-methyl-pentanoyl)-4-methyl-5-phenyl-oxazolidin-2-one (2R,3S)-5-Benzyloxy-2-methyl-3-triethylsilanyloxy-pentanoic acid methoxy-methyl-amide [(2R,3R)-3-((1S,2S)-4-Benzyloxy-1-methyl-2-triethylsilanyloxy-butyl)-oxiranyl]-methanol

下游产品

(2R,3R)-2-[(1S,2R,5S,6S,7R,8S)-10-Benzenesulfonyl-2-(3,4-dimethoxy-benzyloxymethoxy)-1,5,7-trimethyl-6,8-bis-triethylsilanyloxy-decyl]-5-methoxy-3-methyl-tetrahydro-furan