百科

(2R,3S,4aR,8aS)-2-[(2R,3S)-2-Benzenesulfonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranylmethyl]-3-(tert-butyl-dimethyl-silanyloxy)-octahydro-pyrano[3,2-b]pyran

(2R,3S,4aR,8aS)-2-[(2R,3S)-2-Benzenesulfonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranylmethyl]-3-(tert-butyl-dimethyl-silanyloxy)-octahydro-pyrano[3,2-b]pyran

CAS号：181208-20-8

英文名：(2R,3S,4aR,8aS)-2-[(2R,3S)-2-Benzenesulfonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranylmethyl]-3-(tert-butyl-dimethyl-silanyloxy)-octahydro-pyrano[3,2-b]pyran

分子式：C40H56O7SSi2

分子量：737.104

合成路线

(2R,4aR,8aS)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-hexahydro-pyrano[3,2-b]pyran-3-one

(2R,4aR,8aS)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-hexahydro-pyrano[3,2-b]pyran-3-one

(2R,3S,4aR,8aS)-2-[(2R,3S)-2-Benzenesulfonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranylmethyl]-3-(tert-butyl-dimethyl-silanyloxy)-octahydro-pyrano[3,2-b]pyran

(2R,3S,4aR,8aS)-2-[(2R,3S)-2-Benzenesulfonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranylmethyl]-3-(tert-butyl-dimethyl-silanyloxy)-octahydro-pyrano[3,2-b]pyran

(Z)-2-((4R)-2,2-diphenyl-1,3-dioxolan-4-yl)vinyl phenyl sulfone

(Z)-2-((4R)-2,2-diphenyl-1,3-dioxolan-4-yl)vinyl phenyl sulfone

(2R,3S,4aR,8aS)-2-[(2R,3S)-2-Benzenesulfonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranylmethyl]-3-(tert-butyl-dimethyl-silanyloxy)-octahydro-pyrano[3,2-b]pyran

(2R,3S,4aR,8aS)-2-[(2R,3S)-2-Benzenesulfonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranylmethyl]-3-(tert-butyl-dimethyl-silanyloxy)-octahydro-pyrano[3,2-b]pyran

(S)-1-((2S,3R)-3-Benzenesulfonyl-oxiranyl)-ethane-1,2-diol

(S)-1-((2S,3R)-3-Benzenesulfonyl-oxiranyl)-ethane-1,2-diol

(2R,3S,4aR,8aS)-2-[(2R,3S)-2-Benzenesulfonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranylmethyl]-3-(tert-butyl-dimethyl-silanyloxy)-octahydro-pyrano[3,2-b]pyran

(2R,3S,4aR,8aS)-2-[(2R,3S)-2-Benzenesulfonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranylmethyl]-3-(tert-butyl-dimethyl-silanyloxy)-octahydro-pyrano[3,2-b]pyran

上游原料

(S)-1-((2S,3R)-3-Benzenesulfonyl-oxiranyl)-ethane-1,2-diol (Z)-2-((4R)-2,2-diphenyl-1,3-dioxolan-4-yl)vinyl phenyl sulfone (2R,4aR,8aS)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-hexahydro-pyrano[3,2-b]pyran-3-one

下游产品

(2R,3S,4aR,8aR,9aS,10aS)-2-[(2R,3S)-2-Benzenesulfonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranylmethyl]-3-(tert-butyl-dimethyl-silanyloxy)-decahydro-1,8,10-trioxa-anthracene (2R,4aR,8aR,9aS,10aS)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-octahydro-1,8,10-trioxa-anthracen-3-one (2R,3S,4aR,8aR,9aS,10aS)-2-Hydroxymethyl-decahydro-1,8,10-trioxa-anthracen-3-ol (2R,4aR,5aS,6aR,10aS,11aR,12aS)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-dodecahydro-1,5,7,11-tetraoxa-naphthacen-3-one