百科

(2R,4aR,6S,7R,8aS,9R,9aR,10aR)-9-(tert-Butyl-dimethyl-silanyloxy)-7-(2-hydroxy-ethyl)-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-6-ol

(2R,4aR,6S,7R,8aS,9R,9aR,10aR)-9-(tert-Butyl-dimethyl-silanyloxy)-7-(2-hydroxy-ethyl)-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-6-ol

CAS号：181267-32-3

英文名：(2R,4aR,6S,7R,8aS,9R,9aR,10aR)-9-(tert-Butyl-dimethyl-silanyloxy)-7-(2-hydroxy-ethyl)-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-6-ol

分子式：C24H38O7Si

分子量：466.64

合成路线

((2R,4aR,6S,7R,8aR,9R,9aS,10aR)-6-Acetoxy-9-hydroxy-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-acetic acid methyl ester

((2R,4aR,6S,7R,8aR,9R,9aS,10aR)-6-Acetoxy-9-hydroxy-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-acetic acid methyl ester

(2R,4aR,6S,7R,8aS,9R,9aR,10aR)-9-(tert-Butyl-dimethyl-silanyloxy)-7-(2-hydroxy-ethyl)-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-6-ol

(2R,4aR,6S,7R,8aS,9R,9aR,10aR)-9-(tert-Butyl-dimethyl-silanyloxy)-7-(2-hydroxy-ethyl)-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-6-ol

(E)-(S)-4-Acetoxy-5-((2R,4aR,6R,7R,8R,8aS)-7,8-dihydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-pent-2-enoic acid methyl ester

(E)-(S)-4-Acetoxy-5-((2R,4aR,6R,7R,8R,8aS)-7,8-dihydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-pent-2-enoic acid methyl ester

(2R,4aR,6S,7R,8aS,9R,9aR,10aR)-9-(tert-Butyl-dimethyl-silanyloxy)-7-(2-hydroxy-ethyl)-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-6-ol

(2R,4aR,6S,7R,8aS,9R,9aR,10aR)-9-(tert-Butyl-dimethyl-silanyloxy)-7-(2-hydroxy-ethyl)-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-6-ol

(E)-(S)-5-[(2R,4aR,6R,7S,8S,8aR)-7,8-Bis-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-4-hydroxy-pent-2-enoic acid methyl ester

(E)-(S)-5-[(2R,4aR,6R,7S,8S,8aR)-7,8-Bis-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-4-hydroxy-pent-2-enoic acid methyl ester

(2R,4aR,6S,7R,8aS,9R,9aR,10aR)-9-(tert-Butyl-dimethyl-silanyloxy)-7-(2-hydroxy-ethyl)-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-6-ol

(2R,4aR,6S,7R,8aS,9R,9aR,10aR)-9-(tert-Butyl-dimethyl-silanyloxy)-7-(2-hydroxy-ethyl)-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-6-ol

(E)-(S)-4-Acetoxy-5-[(2R,4aR,6R,7S,8S,8aR)-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-pent-2-enoic acid methyl ester

(E)-(S)-4-Acetoxy-5-[(2R,4aR,6R,7S,8S,8aR)-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-pent-2-enoic acid methyl ester

(2R,4aR,6S,7R,8aS,9R,9aR,10aR)-9-(tert-Butyl-dimethyl-silanyloxy)-7-(2-hydroxy-ethyl)-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-6-ol

(2R,4aR,6S,7R,8aS,9R,9aR,10aR)-9-(tert-Butyl-dimethyl-silanyloxy)-7-(2-hydroxy-ethyl)-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-6-ol

上游原料

(E)-(S)-4-Acetoxy-5-((2R,4aR,6R,7R,8R,8aS)-7,8-dihydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-pent-2-enoic acid methyl ester (E)-(S)-5-[(2R,4aR,6R,7S,8S,8aR)-7,8-Bis-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-4-hydroxy-pent-2-enoic acid methyl ester (E)-(S)-4-Acetoxy-5-[(2R,4aR,6R,7S,8S,8aR)-7,8-bis-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-pent-2-enoic acid methyl ester ((2R,4aR,6S,7R,8aR,9R,9aS,10aR)-6-Acetoxy-9-hydroxy-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-acetic acid methyl ester

下游产品

[(2R,3R,4S,4aS,6R,7S,8aR)-3,4,7-Tris-benzyloxy-6-(2-methoxy-ethyl)-octahydro-pyrano[3,2-b]pyran-2-yl]-acetonitrile (2R,4aR,6S,7R,8aS,9R,9aR,10aR)-6,9-Bis-benzyloxy-7-(2-methoxy-ethyl)-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracene [(2R,3R,4S,4aS,6R,7S,8aR)-3,4,7-Tris-benzyloxy-6-(2-methoxy-ethyl)-octahydro-pyrano[3,2-b]pyran-2-yl]-methanol 2-[(2R,4aR,6S,7R,8aS,9R,9aR,10aR)-6,9-Bis-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl]-ethanol (2R,4aR,6S,7R,8aS,9R,9aR,10aR)-6,9-Bis-(tert-butyl-dimethyl-silanyloxy)-7-(2-methoxy-ethyl)-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracene