百科

(2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-4-(4-oxo-pentanoyloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

(2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-4-(4-oxo-pentanoyloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

CAS号：181718-67-2

英文名：(2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-4-(4-oxo-pentanoyloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

分子式：C23H24Cl3NO11

分子量：596.796

合成路线

(2S,3S,4S,5R,6R)-3,4,5-Trihydroxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

(2S,3S,4S,5R,6R)-3,4,5-Trihydroxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

(2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-4-(4-oxo-pentanoyloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

(2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-4-(4-oxo-pentanoyloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

(2S,3S,4S,5R,6R)-3,4,5-Triacetoxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

(2S,3S,4S,5R,6R)-3,4,5-Triacetoxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

(2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-4-(4-oxo-pentanoyloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

(2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-4-(4-oxo-pentanoyloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

(2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-4-hydroxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

(2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-4-hydroxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

(2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-4-(4-oxo-pentanoyloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

(2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-4-(4-oxo-pentanoyloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

(2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-4-(4-oxo-pentanoyloxy)-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

(2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-4-(4-oxo-pentanoyloxy)-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

(2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-4-(4-oxo-pentanoyloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

(2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-4-(4-oxo-pentanoyloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

上游原料

(2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-4-hydroxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester (2S,3S,4S,5R,6R)-3,4,5-Triacetoxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester (2S,3S,4S,5R,6R)-3,4,5-Trihydroxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester (2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-4-(4-oxo-pentanoyloxy)-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

下游产品

(2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-6-[(2R,3S,4S,5R,6R)-3,5-bis-benzoyloxy-2-benzoyloxymethyl-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-4-yloxy]-4-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester (2S,3S,4S,5R,6R)-3-Acetoxy-5-benzoyloxy-6-[(2R,3S,4S,5R,6R)-3,5-bis-benzoyloxy-2-benzoyloxymethyl-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-4-yloxy]-4-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester