百科

(R)-5-[(Z)-(S)-1-(tert-Butyl-diphenyl-silanyloxy)-7-((4R,5S)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-4-enyl]-dihydro-furan-2-one

(R)-5-[(Z)-(S)-1-(tert-Butyl-diphenyl-silanyloxy)-7-((4R,5S)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-4-enyl]-dihydro-furan-2-one

CAS号：182072-82-8

英文名：(R)-5-[(Z)-(S)-1-(tert-Butyl-diphenyl-silanyloxy)-7-((4R,5S)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-4-enyl]-dihydro-furan-2-one

分子式：C42H64O5Si

分子量：677.04

合成路线

(R)-5-((R)-4-Benzyloxy-1-hydroxy-butyl)-dihydro-furan-2-one

(R)-5-((R)-4-Benzyloxy-1-hydroxy-butyl)-dihydro-furan-2-one

(R)-5-[(Z)-(S)-1-(tert-Butyl-diphenyl-silanyloxy)-7-((4R,5S)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-4-enyl]-dihydro-furan-2-one

(R)-5-[(Z)-(S)-1-(tert-Butyl-diphenyl-silanyloxy)-7-((4R,5S)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-4-enyl]-dihydro-furan-2-one

(4R,5S)-1-iodo-4,5-isopropylidenedioxypentadecane

(4R,5S)-1-iodo-4,5-isopropylidenedioxypentadecane

(R)-5-[(Z)-(S)-1-(tert-Butyl-diphenyl-silanyloxy)-7-((4R,5S)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-4-enyl]-dihydro-furan-2-one

(R)-5-[(Z)-(S)-1-(tert-Butyl-diphenyl-silanyloxy)-7-((4R,5S)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-4-enyl]-dihydro-furan-2-one

(4R,5S)-5-(4-nitrobenzoyloxy)pentadecan-1,4-olide

(4R,5S)-5-(4-nitrobenzoyloxy)pentadecan-1,4-olide

(R)-5-[(Z)-(S)-1-(tert-Butyl-diphenyl-silanyloxy)-7-((4R,5S)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-4-enyl]-dihydro-furan-2-one

(R)-5-[(Z)-(S)-1-(tert-Butyl-diphenyl-silanyloxy)-7-((4R,5S)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-4-enyl]-dihydro-furan-2-one

上游原料

(4R,5S)-1-iodo-4,5-isopropylidenedioxypentadecane (R)-5-((R)-4-Benzyloxy-1-hydroxy-butyl)-dihydro-furan-2-one (4R,5S)-5-(4-nitrobenzoyloxy)pentadecan-1,4-olide

下游产品

(2R,2'S,5'S)-5'-[(R)-3-((4R,5S)-5-Decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-hydroxy-propyl]-tetrahydro-[2,2']bifuranyl-5-one