百科

(R)-4-((1S,2S,3R,6R)-6-Methoxymethoxymethyl-2,3-dimethyl-2-phenylsulfanylmethyl-cyclohexyl)-2,2-dimethyl-[1,3]dioxolane

(R)-4-((1S,2S,3R,6R)-6-Methoxymethoxymethyl-2,3-dimethyl-2-phenylsulfanylmethyl-cyclohexyl)-2,2-dimethyl-[1,3]dioxolane

CAS号：182625-03-2

英文名：(R)-4-((1S,2S,3R,6R)-6-Methoxymethoxymethyl-2,3-dimethyl-2-phenylsulfanylmethyl-cyclohexyl)-2,2-dimethyl-[1,3]dioxolane

分子式：C23H36O4S

分子量：408.595

合成路线

2,2-Dimethyl-propionic acid (1S,2S,3S,4R)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-methoxymethoxymethyl-2-methyl-cyclohexylmethyl ester

2,2-Dimethyl-propionic acid (1S,2S,3S,4R)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-methoxymethoxymethyl-2-methyl-cyclohexylmethyl ester

(R)-4-((1S,2S,3R,6R)-6-Methoxymethoxymethyl-2,3-dimethyl-2-phenylsulfanylmethyl-cyclohexyl)-2,2-dimethyl-[1,3]dioxolane

(R)-4-((1S,2S,3R,6R)-6-Methoxymethoxymethyl-2,3-dimethyl-2-phenylsulfanylmethyl-cyclohexyl)-2,2-dimethyl-[1,3]dioxolane

(1R,2S,3S,4S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2-methyl-bicyclo[2.2.2]oct-5-ene-2-carboxylic acid ethyl ester

(1R,2S,3S,4S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2-methyl-bicyclo[2.2.2]oct-5-ene-2-carboxylic acid ethyl ester

(R)-4-((1S,2S,3R,6R)-6-Methoxymethoxymethyl-2,3-dimethyl-2-phenylsulfanylmethyl-cyclohexyl)-2,2-dimethyl-[1,3]dioxolane

(R)-4-((1S,2S,3R,6R)-6-Methoxymethoxymethyl-2,3-dimethyl-2-phenylsulfanylmethyl-cyclohexyl)-2,2-dimethyl-[1,3]dioxolane

[(1R,2S,3S,4R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-methoxymethoxymethyl-2-methyl-cyclohexyl]-methanol

[(1R,2S,3S,4R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-methoxymethoxymethyl-2-methyl-cyclohexyl]-methanol

(R)-4-((1S,2S,3R,6R)-6-Methoxymethoxymethyl-2,3-dimethyl-2-phenylsulfanylmethyl-cyclohexyl)-2,2-dimethyl-[1,3]dioxolane

(R)-4-((1S,2S,3R,6R)-6-Methoxymethoxymethyl-2,3-dimethyl-2-phenylsulfanylmethyl-cyclohexyl)-2,2-dimethyl-[1,3]dioxolane

上游原料

(1R,2S,3S,4S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2-methyl-bicyclo[2.2.2]oct-5-ene-2-carboxylic acid ethyl ester [(1R,2S,3S,4R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-methoxymethoxymethyl-2-methyl-cyclohexyl]-methanol 2,2-Dimethyl-propionic acid (1S,2S,3S,4R)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-methoxymethoxymethyl-2-methyl-cyclohexylmethyl ester

下游产品

[(2E,6E)-(S)-8-((1R,2S,3S,4R)-3-Benzenesulfonylmethyl-2-benzyloxymethyl-3,4-dimethyl-cyclohexyl)-8-benzyloxymethoxy-2,6-dimethyl-octa-2,6-dienyloxy]-tert-butyl-dimethyl-silane ((1S,2S,3R,6R)-2-Benzenesulfonylmethyl-6-methoxymethoxymethyl-2,3-dimethyl-cyclohexyl)-methanol Phomactin D