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(−)-8-deoxyserratinine

(−)-8-deoxyserratinine

CAS号：18331-31-2

英文名：(−)-8-deoxyserratinine

分子式：C16H25NO2

分子量：263.375

合成路线

(3aS,6R,7aR)-3a-allyl-6-methylhexahydrospiro[indene-4,2'-[1,3]dioxolan]-3(3aH)-one

(3aS,6R,7aR)-3a-allyl-6-methylhexahydrospiro[indene-4,2'-[1,3]dioxolan]-3(3aH)-one

(−)-8-deoxyserratinine

(−)-8-deoxyserratinine

(((3R,5R)-3-(2-(1,3-dioxolan-2-yl)ethyl)-2-allyl-5-methylcyclohex-1-en-1-yl)oxy)trimethylsilane

(((3R,5R)-3-(2-(1,3-dioxolan-2-yl)ethyl)-2-allyl-5-methylcyclohex-1-en-1-yl)oxy)trimethylsilane

(−)-8-deoxyserratinine

(−)-8-deoxyserratinine

tert-butyl (7aS,8R,9aS,11R,13R,13aR)-7a,8,13-trihydroxy-11-methyldodecahydro-1H-indeno[1,7a-e]azonine-4(5H)-carboxylate

tert-butyl (7aS,8R,9aS,11R,13R,13aR)-7a,8,13-trihydroxy-11-methyldodecahydro-1H-indeno[1,7a-e]azonine-4(5H)-carboxylate

(−)-8-deoxyserratinine

(−)-8-deoxyserratinine

tert-butyl (7aS,8S,9aS,11R,13R,13aR)-7a,8,13-trihydroxy-11-methyldodecahydro-1H-indeno[1,7a-e]azonine-4(5H)-carboxylate

tert-butyl (7aS,8S,9aS,11R,13R,13aR)-7a,8,13-trihydroxy-11-methyldodecahydro-1H-indeno[1,7a-e]azonine-4(5H)-carboxylate

(−)-8-deoxyserratinine

(−)-8-deoxyserratinine

上游原料

tert-butyl (7aS,8S,9aS,11R,13R,13aR)-7a,8,13-trihydroxy-11-methyldodecahydro-1H-indeno[1,7a-e]azonine-4(5H)-carboxylate tert-butyl (7aS,8R,9aS,11R,13R,13aR)-7a,8,13-trihydroxy-11-methyldodecahydro-1H-indeno[1,7a-e]azonine-4(5H)-carboxylate (3aS,6R,7aR)-3a-allyl-6-methylhexahydrospiro[indene-4,2'-[1,3]dioxolan]-3(3aH)-one (((3R,5R)-3-(2-(1,3-dioxolan-2-yl)ethyl)-2-allyl-5-methylcyclohex-1-en-1-yl)oxy)trimethylsilane

下游产品

(1S,4R,6S,9S)-4,13-Dimethyl-13-aza-tricyclo[7.7.0.01,6]hexadecane-2,8-dione