百科

1-((3S,5R,8R,9S,10S,13R,14S,17S)-3-((tert-butyldimethylsilyl)oxy)-14-hydroxy-10,13-dimethylhexadecahydro-1H-cyclopenta[a]phenanthren-17-yl)-2-hydroxyethan-1-one

CAS号：183615-63-6

英文名：1-((3S,5R,8R,9S,10S,13R,14S,17S)-3-((tert-butyldimethylsilyl)oxy)-14-hydroxy-10,13-dimethylhexadecahydro-1H-cyclopenta[a]phenanthren-17-yl)-2-hydroxyethan-1-one

分子式：C27H48O4Si

分子量：464.753

合成路线

101053-28-5

(1S,6R)-8,8-ethylenedioxy-1-methylbicyclo[4.4.0]decan-2-one

183615-63-6

1-((3S,5R,8R,9S,10S,13R,14S,17S)-3-((tert-butyldimethylsilyl)oxy)-14-hydroxy-10,13-dimethylhexadecahydro-1H-cyclopenta[a]phenanthren-17-yl)-2-hydroxyethan-1-one

183615-38-5

(7R,8S)-8-methyl-7-(3-oxopropyl)-1,4-dioxaspiro[4.5]decane-8-carbaldehyde

183615-63-6

1-((3S,5R,8R,9S,10S,13R,14S,17S)-3-((tert-butyldimethylsilyl)oxy)-14-hydroxy-10,13-dimethylhexadecahydro-1H-cyclopenta[a]phenanthren-17-yl)-2-hydroxyethan-1-one

183615-40-9

(7R,8S)-7-(3-hydroxypropyl)-8-methyl-1,4-dioxaspiro[4.5]decane-8-carbaldehyde

183615-63-6

1-((3S,5R,8R,9S,10S,13R,14S,17S)-3-((tert-butyldimethylsilyl)oxy)-14-hydroxy-10,13-dimethylhexadecahydro-1H-cyclopenta[a]phenanthren-17-yl)-2-hydroxyethan-1-one

183815-03-4

3-((7R,8S)-8-methyl-8-((1E,3E)-penta-1,3-dien-1-yl)-1,4-dioxaspiro[4.5]decan-7-yl)propanal

183615-63-6

1-((3S,5R,8R,9S,10S,13R,14S,17S)-3-((tert-butyldimethylsilyl)oxy)-14-hydroxy-10,13-dimethylhexadecahydro-1H-cyclopenta[a]phenanthren-17-yl)-2-hydroxyethan-1-one

183615-65-8

trimethyl(((4aS,8aR)-4a-methyl-3,4,4a,7,8,8a-hexahydro-1H-spiro[naphthalene-2,2'-[1,3]dioxolan]-5-yl)oxy)silane

183615-63-6

1-((3S,5R,8R,9S,10S,13R,14S,17S)-3-((tert-butyldimethylsilyl)oxy)-14-hydroxy-10,13-dimethylhexadecahydro-1H-cyclopenta[a]phenanthren-17-yl)-2-hydroxyethan-1-one

上游原料

(7R,8S)-8-methyl-7-(3-oxopropyl)-1,4-dioxaspiro[4.5]decane-8-carbaldehyde trimethyl(((4aS,8aR)-4a-methyl-3,4,4a,7,8,8a-hexahydro-1H-spiro[naphthalene-2,2'-[1,3]dioxolan]-5-yl)oxy)silane (7R,8S)-7-(3-hydroxypropyl)-8-methyl-1,4-dioxaspiro[4.5]decane-8-carbaldehyde 3-((7R,8S)-8-methyl-8-((1E,3E)-penta-1,3-dien-1-yl)-1,4-dioxaspiro[4.5]decan-7-yl)propanal (1S,6R)-8,8-ethylenedioxy-1-methylbicyclo[4.4.0]decan-2-one

下游产品

毛地黄毒苷配基