百科

(1R,3aS,7aR)-4-[(1S,3S,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-bicyclo[3.1.0]hex-1-ylethynyl]-1-((R)-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-4-ol

CAS号：183812-81-9

英文名：(1R,3aS,7aR)-4-[(1S,3S,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-bicyclo[3.1.0]hex-1-ylethynyl]-1-((R)-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-4-ol

分子式：C42H60O2Si

分子量：625.01

合成路线

75197-02-3

14,14-epi-Grundmann's ketone3

183559-11-7

tert-Butyl-((1S,3S,5S)-1-ethynyl-bicyclo[3.1.0]hex-3-yloxy)-diphenyl-silane

183812-81-9

(1R,3aS,7aR)-4-[(1S,3S,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-bicyclo[3.1.0]hex-1-ylethynyl]-1-((R)-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-4-ol

183559-06-0

((S)-1-Bromomethyl-2-(S)-oxiranyl-ethoxy)-tert-butyl-diphenyl-silane

183812-81-9

(1R,3aS,7aR)-4-[(1S,3S,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-bicyclo[3.1.0]hex-1-ylethynyl]-1-((R)-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-4-ol

183559-10-6

(1S,3S,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-bicyclo[3.1.0]hexane-1-carbonitrile

183812-81-9

(1R,3aS,7aR)-4-[(1S,3S,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-bicyclo[3.1.0]hex-1-ylethynyl]-1-((R)-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-4-ol

182802-00-2

(1S,3S,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-bicyclo[3.1.0]hexane-1-carbaldehyde

183812-81-9

(1R,3aS,7aR)-4-[(1S,3S,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-bicyclo[3.1.0]hex-1-ylethynyl]-1-((R)-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-4-ol

上游原料

(1S,3S,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-bicyclo[3.1.0]hexane-1-carbaldehyde tert-Butyl-((1S,3S,5S)-1-ethynyl-bicyclo[3.1.0]hex-3-yloxy)-diphenyl-silane 14,14-epi-Grundmann's ketone3 (1S,3S,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-bicyclo[3.1.0]hexane-1-carbonitrile ((S)-1-Bromomethyl-2-(S)-oxiranyl-ethoxy)-tert-butyl-diphenyl-silane

下游产品

(1R,3aS,7aR)-4-{(E)-2-[(1S,3S,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-bicyclo[3.1.0]hex-1-yl]-vinyl}-1-((R)-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-4-ol