百科

(2R,3S,4R,5R,6R)-5-azido-4-(((2R,3R,4R,5S,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-3-hydroxytetrahydro-2H-pyran-2-yl)oxy)-2-(hydroxymethyl)-6-(phenylthio)tetrahydro-2H-pyran-3-ol

(2R,3S,4R,5R,6R)-5-azido-4-(((2R,3R,4R,5S,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-3-hydroxytetrahydro-2H-pyran-2-yl)oxy)-2-(hydroxymethyl)-6-(phenylthio)tetrahydro-2H-pyran-3-ol

CAS号：183875-32-3

英文名：(2R,3S,4R,5R,6R)-5-azido-4-(((2R,3R,4R,5S,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-3-hydroxytetrahydro-2H-pyran-2-yl)oxy)-2-(hydroxymethyl)-6-(phenylthio)tetrahydro-2H-pyran-3-ol

分子式：C39H43N3O9S

分子量：729.838

合成路线

phenyl 2-azido-2-deoxy-1-thio-α/β-D-glucopyranoside

phenyl 2-azido-2-deoxy-1-thio-α/β-D-glucopyranoside

(2R,3S,4R,5R,6R)-5-azido-4-(((2R,3R,4R,5S,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-3-hydroxytetrahydro-2H-pyran-2-yl)oxy)-2-(hydroxymethyl)-6-(phenylthio)tetrahydro-2H-pyran-3-ol

(2R,3S,4R,5R,6R)-5-azido-4-(((2R,3R,4R,5S,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-3-hydroxytetrahydro-2H-pyran-2-yl)oxy)-2-(hydroxymethyl)-6-(phenylthio)tetrahydro-2H-pyran-3-ol

phenyl 2-deoxy-2-azido-4,6-O-benzylidenethio-α-D-glucopyranoside

phenyl 2-deoxy-2-azido-4,6-O-benzylidenethio-α-D-glucopyranoside

(2R,3S,4R,5R,6R)-5-azido-4-(((2R,3R,4R,5S,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-3-hydroxytetrahydro-2H-pyran-2-yl)oxy)-2-(hydroxymethyl)-6-(phenylthio)tetrahydro-2H-pyran-3-ol

(2R,3S,4R,5R,6R)-5-azido-4-(((2R,3R,4R,5S,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-3-hydroxytetrahydro-2H-pyran-2-yl)oxy)-2-(hydroxymethyl)-6-(phenylthio)tetrahydro-2H-pyran-3-ol

2,2-Dimethyl-propionic acid (2R,3R,4S,5S,6R)-2-((2R,3R,4R,5S,6R)-3-azido-5-hydroxy-6-hydroxymethyl-2-phenylsulfanyl-tetrahydro-pyran-4-yloxy)-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester

2,2-Dimethyl-propionic acid (2R,3R,4S,5S,6R)-2-((2R,3R,4R,5S,6R)-3-azido-5-hydroxy-6-hydroxymethyl-2-phenylsulfanyl-tetrahydro-pyran-4-yloxy)-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester

(2R,3S,4R,5R,6R)-5-azido-4-(((2R,3R,4R,5S,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-3-hydroxytetrahydro-2H-pyran-2-yl)oxy)-2-(hydroxymethyl)-6-(phenylthio)tetrahydro-2H-pyran-3-ol

(2R,3S,4R,5R,6R)-5-azido-4-(((2R,3R,4R,5S,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-3-hydroxytetrahydro-2H-pyran-2-yl)oxy)-2-(hydroxymethyl)-6-(phenylthio)tetrahydro-2H-pyran-3-ol

phenyl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-β-D-galactopyranoside

phenyl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-β-D-galactopyranoside

(2R,3S,4R,5R,6R)-5-azido-4-(((2R,3R,4R,5S,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-3-hydroxytetrahydro-2H-pyran-2-yl)oxy)-2-(hydroxymethyl)-6-(phenylthio)tetrahydro-2H-pyran-3-ol

(2R,3S,4R,5R,6R)-5-azido-4-(((2R,3R,4R,5S,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-3-hydroxytetrahydro-2H-pyran-2-yl)oxy)-2-(hydroxymethyl)-6-(phenylthio)tetrahydro-2H-pyran-3-ol

上游原料

2,2-Dimethyl-propionic acid (2R,3R,4S,5S,6R)-2-((2R,3R,4R,5S,6R)-3-azido-5-hydroxy-6-hydroxymethyl-2-phenylsulfanyl-tetrahydro-pyran-4-yloxy)-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester phenyl 2-azido-2-deoxy-1-thio-α/β-D-glucopyranoside phenyl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-β-D-galactopyranoside phenyl 2-deoxy-2-azido-4,6-O-benzylidenethio-α-D-glucopyranoside

下游产品

methyl (2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-(2,3,4-tri-O-acetyl-α-L-fucopyranosyl)-(1->3)-6-O-acetyl-2-acetamido-2-deoxy-β-D-glucopyranoside Acetic acid (2R,3S,4R,5R,6R)-5-azido-6-phenylsulfanyl-3-((2S,3R,4S,5S,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-4-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-ylmethyl ester