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(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

CAS号：185155-28-6

英文名：(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

分子式：C38H52O12

分子量：700.812

合成路线

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-but-3-enyl-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid di-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-but-3-enyl-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid di-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-hydroxy-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-hydroxy-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

1,6-Anhydro-2,3-di-O-benzyl-4-(hydroxymethyl)-β-D-galactopyranose

1,6-Anhydro-2,3-di-O-benzyl-4-(hydroxymethyl)-β-D-galactopyranose

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

1,6-Anhydro-2,3-di-O-benzyl-4-<<(tert-butyldiphenylsilyl)oxy>methyl>-β-D-galactopyranose

1,6-Anhydro-2,3-di-O-benzyl-4-<<(tert-butyldiphenylsilyl)oxy>methyl>-β-D-galactopyranose

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3R,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-but-3-enyl-3,5-bis-hydroxymethyl-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octan-4-ol

(1S,3R,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-but-3-enyl-3,5-bis-hydroxymethyl-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octan-4-ol

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-but-3-enyl-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarbaldehyde

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-but-3-enyl-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarbaldehyde

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-formyl-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid di-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-formyl-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid di-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-hydroxy-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid 3,5-di-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-hydroxy-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid 3,5-di-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3R,5R,6R,7R)-6,7-Bis-benzyloxy-1-but-3-enyl-3-(tert-butyl-dimethyl-silanyloxymethyl)-5-(tert-butyl-diphenyl-silanyloxymethyl)-2,8-dioxa-bicyclo[3.2.1]octan-4-one

(1S,3R,5R,6R,7R)-6,7-Bis-benzyloxy-1-but-3-enyl-3-(tert-butyl-dimethyl-silanyloxymethyl)-5-(tert-butyl-diphenyl-silanyloxymethyl)-2,8-dioxa-bicyclo[3.2.1]octan-4-one

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3R,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-but-3-enyl-3-(tert-butyl-dimethyl-silanyloxymethyl)-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octan-4-ol

(1S,3R,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-but-3-enyl-3-(tert-butyl-dimethyl-silanyloxymethyl)-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octan-4-ol

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

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上游原料

(1S,3R,5R,6R,7R)-6,7-Bis-benzyloxy-1-but-3-enyl-3-(tert-butyl-dimethyl-silanyloxymethyl)-5-(tert-butyl-diphenyl-silanyloxymethyl)-2,8-dioxa-bicyclo[3.2.1]octan-4-one (1S,3R,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-but-3-enyl-3-(tert-butyl-dimethyl-silanyloxymethyl)-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octan-4-ol (1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-but-3-enyl-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarbaldehyde (1S,5R,6R,7R)-6,7-Bis-benzyloxy-1-but-3-enyl-5-(tert-butyl-diphenyl-silanyloxymethyl)-2,8-dioxa-bicyclo[3.2.1]octan-4-one (1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-but-3-enyl-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid (1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-but-3-enyl-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid di-tert-butyl ester (1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-hydroxy-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid 3,5-di-tert-butyl ester 1,6-Anhydro-2,3-di-O-benzyl-4-<<(tert-butyldiphenylsilyl)oxy>methyl>-β-D-galactopyranose (1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-4-formyl-4-hydroxy-1-(3-hydroxy-propyl)-2,8-dioxa-bicyclo[3.2.1]octane-3,5-dicarboxylic acid di-tert-butyl ester (1S,3R,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-but-3-enyl-3,5-bis-hydroxymethyl-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octan-4-ol 1,6-Anhydro-2,3-di-O-benzyl-4-(hydroxymethyl)-β-D-galactopyranose (1S,3S,4S,5R,6R,7R)-6,7-Bis-benzyloxy-1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-hydroxy-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

下游产品

(1S-(1α,3α,4β,5α,6α,7β))-1-(3,3-dimethoxypropyl)-4,6,7-trihydroxy-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylic acid 3,4,5-tris(1,1-dimethylethyl) ester