百科

(R)-2-[(4R,5S,6S)-2,2-Di-tert-butyl-6-((1S,5R,6R,7R)-6-methoxy-1,5,7-trimethyl-4-oxo-9-triisopropylsilanyloxy-nonyl)-5-methyl-[1,3,2]dioxasilinan-4-yl]-propionaldehyde

(R)-2-[(4R,5S,6S)-2,2-Di-tert-butyl-6-((1S,5R,6R,7R)-6-methoxy-1,5,7-trimethyl-4-oxo-9-triisopropylsilanyloxy-nonyl)-5-methyl-[1,3,2]dioxasilinan-4-yl]-propionaldehyde

CAS号：186036-46-4

英文名：(R)-2-[(4R,5S,6S)-2,2-Di-tert-butyl-6-((1S,5R,6R,7R)-6-methoxy-1,5,7-trimethyl-4-oxo-9-triisopropylsilanyloxy-nonyl)-5-methyl-[1,3,2]dioxasilinan-4-yl]-propionaldehyde

分子式：C37H74O6Si2

分子量：671.151

合成路线

(S)-4-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-pentanal

(S)-4-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-pentanal

(R)-2-[(4R,5S,6S)-2,2-Di-tert-butyl-6-((1S,5R,6R,7R)-6-methoxy-1,5,7-trimethyl-4-oxo-9-triisopropylsilanyloxy-nonyl)-5-methyl-[1,3,2]dioxasilinan-4-yl]-propionaldehyde

(R)-2-[(4R,5S,6S)-2,2-Di-tert-butyl-6-((1S,5R,6R,7R)-6-methoxy-1,5,7-trimethyl-4-oxo-9-triisopropylsilanyloxy-nonyl)-5-methyl-[1,3,2]dioxasilinan-4-yl]-propionaldehyde

(4S,5S,6S)-4-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-6-[(1S,4S,5S,6R,7R)-6-methoxy-4-(4-methoxy-benzyloxy)-1,5,7-trimethyl-9-triisopropylsilanyloxy-nonyl]-5-methyl-[1,3,2]dioxasilinane

(4S,5S,6S)-4-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-6-[(1S,4S,5S,6R,7R)-6-methoxy-4-(4-methoxy-benzyloxy)-1,5,7-trimethyl-9-triisopropylsilanyloxy-nonyl]-5-methyl-[1,3,2]dioxasilinane

(R)-2-[(4R,5S,6S)-2,2-Di-tert-butyl-6-((1S,5R,6R,7R)-6-methoxy-1,5,7-trimethyl-4-oxo-9-triisopropylsilanyloxy-nonyl)-5-methyl-[1,3,2]dioxasilinan-4-yl]-propionaldehyde

(R)-2-[(4R,5S,6S)-2,2-Di-tert-butyl-6-((1S,5R,6R,7R)-6-methoxy-1,5,7-trimethyl-4-oxo-9-triisopropylsilanyloxy-nonyl)-5-methyl-[1,3,2]dioxasilinan-4-yl]-propionaldehyde

(2S,3S,4S,5S,6S,9S,10R)-1-Benzyloxy-9-(4-methoxy-benzyloxy)-2,4,6,10-tetramethyl-dodec-11-ene-3,5-diol

(2S,3S,4S,5S,6S,9S,10R)-1-Benzyloxy-9-(4-methoxy-benzyloxy)-2,4,6,10-tetramethyl-dodec-11-ene-3,5-diol

(R)-2-[(4R,5S,6S)-2,2-Di-tert-butyl-6-((1S,5R,6R,7R)-6-methoxy-1,5,7-trimethyl-4-oxo-9-triisopropylsilanyloxy-nonyl)-5-methyl-[1,3,2]dioxasilinan-4-yl]-propionaldehyde

(R)-2-[(4R,5S,6S)-2,2-Di-tert-butyl-6-((1S,5R,6R,7R)-6-methoxy-1,5,7-trimethyl-4-oxo-9-triisopropylsilanyloxy-nonyl)-5-methyl-[1,3,2]dioxasilinan-4-yl]-propionaldehyde

81520-08-3

(R)-2-[(4R,5S,6S)-2,2-Di-tert-butyl-6-((1S,5R,6R,7R)-6-methoxy-1,5,7-trimethyl-4-oxo-9-triisopropylsilanyloxy-nonyl)-5-methyl-[1,3,2]dioxasilinan-4-yl]-propionaldehyde

(R)-2-[(4R,5S,6S)-2,2-Di-tert-butyl-6-((1S,5R,6R,7R)-6-methoxy-1,5,7-trimethyl-4-oxo-9-triisopropylsilanyloxy-nonyl)-5-methyl-[1,3,2]dioxasilinan-4-yl]-propionaldehyde

(2R,3R,4R,5S,6S)-7-benzyloxy-2,3-epoxy-5-triethylsilyloxy-4,6-dimethyl-1-heptanol

(2R,3R,4R,5S,6S)-7-benzyloxy-2,3-epoxy-5-triethylsilyloxy-4,6-dimethyl-1-heptanol

(R)-2-[(4R,5S,6S)-2,2-Di-tert-butyl-6-((1S,5R,6R,7R)-6-methoxy-1,5,7-trimethyl-4-oxo-9-triisopropylsilanyloxy-nonyl)-5-methyl-[1,3,2]dioxasilinan-4-yl]-propionaldehyde

(R)-2-[(4R,5S,6S)-2,2-Di-tert-butyl-6-((1S,5R,6R,7R)-6-methoxy-1,5,7-trimethyl-4-oxo-9-triisopropylsilanyloxy-nonyl)-5-methyl-[1,3,2]dioxasilinan-4-yl]-propionaldehyde

上游原料

(2S,3S,4S,5S,6S,9S,10R)-1-Benzyloxy-9-(4-methoxy-benzyloxy)-2,4,6,10-tetramethyl-dodec-11-ene-3,5-diol (2R,3R,4R,5S,6S)-7-benzyloxy-2,3-epoxy-5-triethylsilyloxy-4,6-dimethyl-1-heptanol (S)-4-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-pentanal (4S,5S,6S)-4-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-6-[(1S,4S,5S,6R,7R)-6-methoxy-4-(4-methoxy-benzyloxy)-1,5,7-trimethyl-9-triisopropylsilanyloxy-nonyl]-5-methyl-[1,3,2]dioxasilinane

下游产品