百科

4-Methyl-N-((S)-1-{(2S,5S)-5-[(E)-(S)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-hept-4-enyl]-tetrahydro-furan-2-yl}-ethyl)-benzenesulfonamide

4-Methyl-N-((S)-1-{(2S,5S)-5-[(E)-(S)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-hept-4-enyl]-tetrahydro-furan-2-yl}-ethyl)-benzenesulfonamide

CAS号：186040-08-4

英文名：4-Methyl-N-((S)-1-{(2S,5S)-5-[(E)-(S)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-hept-4-enyl]-tetrahydro-furan-2-yl}-ethyl)-benzenesulfonamide

分子式：C30H51NO6SSi

分子量：581.88

合成路线

N-((S)-1-{(2S,5S)-5-[(E)-1-Hydroxy-2-(toluene-4-sulfonyl)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-hept-4-enyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide

N-((S)-1-{(2S,5S)-5-[(E)-1-Hydroxy-2-(toluene-4-sulfonyl)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-hept-4-enyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide

4-Methyl-N-((S)-1-{(2S,5S)-5-[(E)-(S)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-hept-4-enyl]-tetrahydro-furan-2-yl}-ethyl)-benzenesulfonamide

4-Methyl-N-((S)-1-{(2S,5S)-5-[(E)-(S)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-hept-4-enyl]-tetrahydro-furan-2-yl}-ethyl)-benzenesulfonamide

4-Methyl-N-((S)-1-{(2S,5S)-5-[(E)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-hept-4-enoyl]-tetrahydro-furan-2-yl}-ethyl)-benzenesulfonamide

4-Methyl-N-((S)-1-{(2S,5S)-5-[(E)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-hept-4-enoyl]-tetrahydro-furan-2-yl}-ethyl)-benzenesulfonamide

4-Methyl-N-((S)-1-{(2S,5S)-5-[(E)-(S)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-hept-4-enyl]-tetrahydro-furan-2-yl}-ethyl)-benzenesulfonamide

4-Methyl-N-((S)-1-{(2S,5S)-5-[(E)-(S)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-hept-4-enyl]-tetrahydro-furan-2-yl}-ethyl)-benzenesulfonamide

(2R,3S)-1-benzyloxy-2-methylhex-5-en-3-ol

(2R,3S)-1-benzyloxy-2-methylhex-5-en-3-ol

4-Methyl-N-((S)-1-{(2S,5S)-5-[(E)-(S)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-hept-4-enyl]-tetrahydro-furan-2-yl}-ethyl)-benzenesulfonamide

4-Methyl-N-((S)-1-{(2S,5S)-5-[(E)-(S)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-hept-4-enyl]-tetrahydro-furan-2-yl}-ethyl)-benzenesulfonamide

上游原料

4-Methyl-N-((S)-1-{(2S,5S)-5-[(E)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-hept-4-enoyl]-tetrahydro-furan-2-yl}-ethyl)-benzenesulfonamide N-((S)-1-{(2S,5S)-5-[(E)-1-Hydroxy-2-(toluene-4-sulfonyl)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-hept-4-enyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide (2R,3S)-1-benzyloxy-2-methylhex-5-en-3-ol

下游产品

Methanesulfonic acid (1R,2R,5S,6R)-5,7-dihydroxy-1-((S)-3-hydroxy-3-{(2S,5S)-5-[(S)-1-(toluene-4-sulfonylamino)-ethyl]-tetrahydro-furan-2-yl}-propyl)-2-methanesulfonyloxy-6-methyl-heptyl ester N-((S)-1-{(2S,5S)-5-[(1S,4R,5R)-4,5-Dihydroxy-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-heptyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide