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N-((S)-1-{(2S,5S)-5-[(1S,4R,5R)-4,5-Dihydroxy-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-heptyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide

CAS号：186040-09-5

英文名：N-((S)-1-{(2S,5S)-5-[(1S,4R,5R)-4,5-Dihydroxy-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-heptyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide

分子式：C30H53NO8SSi

分子量：615.894

合成路线

186642-23-9

N-((S)-1-{(2S,5S)-5-[(E)-1-Hydroxy-2-(toluene-4-sulfonyl)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-hept-4-enyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide

186040-09-5

N-((S)-1-{(2S,5S)-5-[(1S,4R,5R)-4,5-Dihydroxy-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-heptyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide

186040-07-3

4-Methyl-N-((S)-1-{(2S,5S)-5-[(E)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-hept-4-enoyl]-tetrahydro-furan-2-yl}-ethyl)-benzenesulfonamide

186040-09-5

N-((S)-1-{(2S,5S)-5-[(1S,4R,5R)-4,5-Dihydroxy-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-heptyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide

186040-08-4

4-Methyl-N-((S)-1-{(2S,5S)-5-[(E)-(S)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-hept-4-enyl]-tetrahydro-furan-2-yl}-ethyl)-benzenesulfonamide

186040-09-5

N-((S)-1-{(2S,5S)-5-[(1S,4R,5R)-4,5-Dihydroxy-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-heptyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide

85471-45-0

3-hydroxy-1-(5-hydroxy-13,24,33,43,54,63-hexaoxin-2-yl)-16,33,44,51-pentaoxidane-1,1,4-trione

186040-09-5

N-((S)-1-{(2S,5S)-5-[(1S,4R,5R)-4,5-Dihydroxy-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-heptyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide

94233-74-6

(2R,3S)-1-benzyloxy-2-methylhex-5-en-3-ol

186040-09-5

N-((S)-1-{(2S,5S)-5-[(1S,4R,5R)-4,5-Dihydroxy-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-heptyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide

143005-14-5

186040-09-5

N-((S)-1-{(2S,5S)-5-[(1S,4R,5R)-4,5-Dihydroxy-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-heptyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide

142929-78-0

186040-09-5

N-((S)-1-{(2S,5S)-5-[(1S,4R,5R)-4,5-Dihydroxy-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-heptyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide

182822-68-0

(2R,3S)-2-Methyl-hex-5-ene-1,3-diol

186040-09-5

N-((S)-1-{(2S,5S)-5-[(1S,4R,5R)-4,5-Dihydroxy-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-heptyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide

186040-02-8

(4S,5R)-4-(2-Bromo-ethyl)-2,2,5-trimethyl-[1,3]dioxane

186040-09-5

N-((S)-1-{(2S,5S)-5-[(1S,4R,5R)-4,5-Dihydroxy-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-heptyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide

186039-99-6

(2S,5S,1'S)-5-hydroxymethyl-2-[1'-(N-tosylamino)ethyl]tetrahydrofuran

186040-09-5

N-((S)-1-{(2S,5S)-5-[(1S,4R,5R)-4,5-Dihydroxy-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-heptyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide

上游原料

4-Methyl-N-((S)-1-{(2S,5S)-5-[(E)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-hept-4-enoyl]-tetrahydro-furan-2-yl}-ethyl)-benzenesulfonamide (4S,5R)-4-(2-Bromo-ethyl)-2,2,5-trimethyl-[1,3]dioxane 4-Methyl-N-((S)-1-{(2S,5S)-5-[(E)-(S)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-1-trimethylsilanyloxy-hept-4-enyl]-tetrahydro-furan-2-yl}-ethyl)-benzenesulfonamide N-((S)-1-{(2S,5S)-5-[(E)-(S)-1-Hydroxy-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-hept-4-enyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide (4S,5R)-2,2,5-Trimethyl-4-[(E)-6-(toluene-4-sulfonyl)-hex-3-enyl]-[1,3]dioxane 4-Methyl-N-((S)-1-{(2S,5S)-5-[(E)-2-(toluene-4-sulfonyl)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-hept-4-enoyl]-tetrahydro-furan-2-yl}-ethyl)-benzenesulfonamide (2R,3S)-1-benzyloxy-2-methylhex-5-en-3-ol (E)-6-((4S,5R)-2,2,5-Trimethyl-[1,3]dioxan-4-yl)-hex-3-en-1-ol (4S,5R)-4-((E)-6-Bromo-hex-3-enyl)-2,2,5-trimethyl-[1,3]dioxane (2R,3S)-2-Methyl-hex-5-ene-1,3-diol N-((S)-1-{(2S,5S)-5-[(E)-1-Hydroxy-2-(toluene-4-sulfonyl)-7-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-hept-4-enyl]-tetrahydro-furan-2-yl}-ethyl)-4-methyl-benzenesulfonamide (2S,3S)-2-N-tosylamino-6-hepten-3-ol (2S,5S,1'S)-5-hydroxymethyl-2-[1'-(N-tosylamino)ethyl]tetrahydrofuran (2S)-2-N-tosylamino-6-hepten-3-one

下游产品

N-{(S)-1-[(2S,5S,2'S,5'S,2''S,5''S)-5''-((R)-2-Hydroxy-1-methyl-ethyl)-dodecahydro-[2,2';5',2'']terfuran-5-yl]-ethyl}-4-methyl-benzenesulfonamide Methanesulfonic acid (1R,2R,5S,6R)-5,7-dihydroxy-1-((S)-3-hydroxy-3-{(2S,5S)-5-[(S)-1-(toluene-4-sulfonylamino)-ethyl]-tetrahydro-furan-2-yl}-propyl)-2-methanesulfonyloxy-6-methyl-heptyl ester {(S)-1-[(2S,5S,2'S,5'S,2''S,5''S)-5''-((R)-2-Hydroxy-1-methyl-ethyl)-dodecahydro-[2,2';5',2'']terfuran-5-yl]-ethyl}-carbamic acid tert-butyl ester (S)-2-[(2S,5S,2'S,5'S,2''S,5''S)-5''-((S)-1-tert-Butoxycarbonylamino-ethyl)-dodecahydro-[2,2';5',2'']terfuran-5-yl]-propionic acid