百科

(E)-(1S,2R,5R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-{2-[(1R,3S)-4-(tert-butyl-diphenyl-silanyloxy)-1,3-dimethyl-butyl]-[1,3]dithian-2-yl}-5-[1,3]dithian-2-yl-3-methyl-hex-3-en-1-ol

CAS号：186448-91-9

英文名：(E)-(1S,2R,5R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-{2-[(1R,3S)-4-(tert-butyl-diphenyl-silanyloxy)-1,3-dimethyl-butyl]-[1,3]dithian-2-yl}-5-[1,3]dithian-2-yl-3-methyl-hex-3-en-1-ol

分子式：C43H70O3S4Si2

分子量：819.445

合成路线

157837-63-3

(2R,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-2,4-dimethyl-pentanoic acid methyl ester

186448-91-9

(E)-(1S,2R,5R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-{2-[(1R,3S)-4-(tert-butyl-diphenyl-silanyloxy)-1,3-dimethyl-butyl]-[1,3]dithian-2-yl}-5-[1,3]dithian-2-yl-3-methyl-hex-3-en-1-ol

858371-81-0

dimethyl 2,4-dimethylpentanedioate

186448-91-9

(E)-(1S,2R,5R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-{2-[(1R,3S)-4-(tert-butyl-diphenyl-silanyloxy)-1,3-dimethyl-butyl]-[1,3]dithian-2-yl}-5-[1,3]dithian-2-yl-3-methyl-hex-3-en-1-ol

157837-48-4

(E)-(2R,5R)-5-[1,3]Dithian-2-yl-3-methyl-hex-3-ene-1,2-diol

186448-91-9

(E)-(1S,2R,5R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-{2-[(1R,3S)-4-(tert-butyl-diphenyl-silanyloxy)-1,3-dimethyl-butyl]-[1,3]dithian-2-yl}-5-[1,3]dithian-2-yl-3-methyl-hex-3-en-1-ol

157837-35-9

(R)-1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-3-[1,3]dithian-2-yl-butan-1-one

186448-91-9

(E)-(1S,2R,5R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-{2-[(1R,3S)-4-(tert-butyl-diphenyl-silanyloxy)-1,3-dimethyl-butyl]-[1,3]dithian-2-yl}-5-[1,3]dithian-2-yl-3-methyl-hex-3-en-1-ol

157837-49-5

2,2-Dimethyl-propionic acid (E)-(2R,5R)-5-[1,3]dithian-2-yl-2-hydroxy-3-methyl-hex-3-enyl ester

186448-91-9

(E)-(1S,2R,5R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-{2-[(1R,3S)-4-(tert-butyl-diphenyl-silanyloxy)-1,3-dimethyl-butyl]-[1,3]dithian-2-yl}-5-[1,3]dithian-2-yl-3-methyl-hex-3-en-1-ol

157837-65-5

(2R,4S)-5-{[tert-butyl(diphenyl)silyl]oxy}-2,4-dimethylpentanal

186448-91-9

(E)-(1S,2R,5R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-{2-[(1R,3S)-4-(tert-butyl-diphenyl-silanyloxy)-1,3-dimethyl-butyl]-[1,3]dithian-2-yl}-5-[1,3]dithian-2-yl-3-methyl-hex-3-en-1-ol

157837-50-8

2,2-Dimethyl-propionic acid (E)-(2R,5R)-2-(tert-butyl-dimethyl-silanyloxy)-5-[1,3]dithian-2-yl-3-methyl-hex-3-enyl ester

186448-91-9

(E)-(1S,2R,5R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-{2-[(1R,3S)-4-(tert-butyl-diphenyl-silanyloxy)-1,3-dimethyl-butyl]-[1,3]dithian-2-yl}-5-[1,3]dithian-2-yl-3-methyl-hex-3-en-1-ol

157837-42-8

Trifluoro-methanesulfonic acid (Z)-(R)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-[1,3]dithian-2-yl-but-1-enyl ester

186448-91-9

(E)-(1S,2R,5R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-{2-[(1R,3S)-4-(tert-butyl-diphenyl-silanyloxy)-1,3-dimethyl-butyl]-[1,3]dithian-2-yl}-5-[1,3]dithian-2-yl-3-methyl-hex-3-en-1-ol

186448-78-2

(R)-2-Benzenesulfonyl-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-[1,3]dithian-2-yl-butan-1-one

186448-91-9

(E)-(1S,2R,5R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-{2-[(1R,3S)-4-(tert-butyl-diphenyl-silanyloxy)-1,3-dimethyl-butyl]-[1,3]dithian-2-yl}-5-[1,3]dithian-2-yl-3-methyl-hex-3-en-1-ol

上游原料

(R)-2-Benzenesulfonyl-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-[1,3]dithian-2-yl-butan-1-one 2,2-Dimethyl-propionic acid (E)-(2R,5R)-2-(tert-butyl-dimethyl-silanyloxy)-5-[1,3]dithian-2-yl-3-methyl-hex-3-enyl ester (E)-(2R,5R)-5-[1,3]Dithian-2-yl-3-methyl-hex-3-ene-1,2-diol Trifluoro-methanesulfonic acid (Z)-(R)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-[1,3]dithian-2-yl-but-1-enyl ester (2R,4S)-5-{[tert-butyl(diphenyl)silyl]oxy}-2,4-dimethylpentanal (R)-1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-3-[1,3]dithian-2-yl-butan-1-one 2,2-Dimethyl-propionic acid (E)-(2R,5R)-5-[1,3]dithian-2-yl-2-hydroxy-3-methyl-hex-3-enyl ester (2R,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-2,4-dimethyl-pentanoic acid methyl ester

下游产品

(2S,4R)-4-{2-[(E)-(1S,2R,5R)-2-(tert-Butyl-dimethyl-silanyloxy)-5-[1,3]dithian-2-yl-1-methoxy-3-methyl-hex-3-enyl]-[1,3]dithian-2-yl}-2-methyl-pentan-1-ol