百科

(3E,5E,7R,8S,9S,11E,13E,15S,16R)-16-((2S,3R,4S)-6-((4R,5S,6R)-2,2-di-tert-butyl-6-ethyl-5-methyl-1,3,2-dioxasilinan-4-yl)-3-hydroxy-4-methyl-5-oxohexan-2-yl)-15-methoxy-3,5,7,9,11-pentamethyl-8-((trimethylsilyl)oxy)oxacyclohexadeca-3,5,11,13-tetraen-2-one

CAS号：186450-85-1

英文名：(3E,5E,7R,8S,9S,11E,13E,15S,16R)-16-((2S,3R,4S)-6-((4R,5S,6R)-2,2-di-tert-butyl-6-ethyl-5-methyl-1,3,2-dioxasilinan-4-yl)-3-hydroxy-4-methyl-5-oxohexan-2-yl)-15-methoxy-3,5,7,9,11-pentamethyl-8-((trimethylsilyl)oxy)oxacyclohexadeca-3,5,11,13-tetraen-2-one

分子式：C45H80O8Si2

分子量：805.283

合成路线

186450-84-0

(3E,5E,11E,13E)-(7R,8S,9S,15S,16R)-16-[(S)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-8-hydroxy-15-methoxy-3,5,7,9,11-pentamethyl-oxacyclohexadeca-3,5,11,13-tetraen-2-one

186450-85-1

(3E,5E,7R,8S,9S,11E,13E,15S,16R)-16-((2S,3R,4S)-6-((4R,5S,6R)-2,2-di-tert-butyl-6-ethyl-5-methyl-1,3,2-dioxasilinan-4-yl)-3-hydroxy-4-methyl-5-oxohexan-2-yl)-15-methoxy-3,5,7,9,11-pentamethyl-8-((trimethylsilyl)oxy)oxacyclohexadeca-3,5,11,13-tetraen-2-one

186425-07-0

(2E,4E,10E,12E)-(6R,7S,8S,14S,15R,16S)-17-(tert-Butyl-diphenyl-silanyloxy)-7,15-dihydroxy-14-methoxy-2,4,6,8,10,16-hexamethyl-heptadeca-2,4,10,12-tetraenoic acid

186450-85-1

上游原料

(2E,4E,10E,12E)-(6R,7S,8S,14S,15R,16S)-17-(tert-Butyl-diphenyl-silanyloxy)-7,15-dihydroxy-14-methoxy-2,4,6,8,10,16-hexamethyl-heptadeca-2,4,10,12-tetraenoic acid (3E,5E,11E,13E)-(7R,8S,9S,15S,16R)-16-[(S)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-8-hydroxy-15-methoxy-3,5,7,9,11-pentamethyl-oxacyclohexadeca-3,5,11,13-tetraen-2-one

下游产品

(2R,4R,5S,6R)-6-ethyl-2-hydroxy-2-((2S,3R,4S)-3-hydroxy-4-((2R,3S,4E,6E,9S,10S,11R,12E,14E)-10-hydroxy-3-methoxy-7,9,11,13,15-pentamethyl-16-oxooxacyclohexadeca-4,6,12,14-tetraen-2-yl)pentan-2-yl)-5-methyltetrahydro-2H-pyran-4-yl (2-iodoethyl) fumarate