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(2RS,3R,4R,5E,7S)-4-(tert-butyldimethylsilyloxy)-1,2-dihydroxy-3,5,7-trimethyl-9-phenyl-5-nonene

(2RS,3R,4R,5E,7S)-4-(tert-butyldimethylsilyloxy)-1,2-dihydroxy-3,5,7-trimethyl-9-phenyl-5-nonene

CAS号：186895-57-8

英文名：(2RS,3R,4R,5E,7S)-4-(tert-butyldimethylsilyloxy)-1,2-dihydroxy-3,5,7-trimethyl-9-phenyl-5-nonene

分子式：C24H42O3Si

分子量：406.674

合成路线

(S)-1,1-dibromo-3-methyl-5-phenyl-1-pentene

(S)-1,1-dibromo-3-methyl-5-phenyl-1-pentene

(2RS,3R,4R,5E,7S)-4-(tert-butyldimethylsilyloxy)-1,2-dihydroxy-3,5,7-trimethyl-9-phenyl-5-nonene

(2RS,3R,4R,5E,7S)-4-(tert-butyldimethylsilyloxy)-1,2-dihydroxy-3,5,7-trimethyl-9-phenyl-5-nonene

(S)-4-methyl-6-phenyl-2-hexyne

(S)-4-methyl-6-phenyl-2-hexyne

(2RS,3R,4R,5E,7S)-4-(tert-butyldimethylsilyloxy)-1,2-dihydroxy-3,5,7-trimethyl-9-phenyl-5-nonene

(2RS,3R,4R,5E,7S)-4-(tert-butyldimethylsilyloxy)-1,2-dihydroxy-3,5,7-trimethyl-9-phenyl-5-nonene

di[(E)-1-hexenyl]chloroborane

di[(E)-1-hexenyl]chloroborane

(2RS,3R,4R,5E,7S)-4-(tert-butyldimethylsilyloxy)-1,2-dihydroxy-3,5,7-trimethyl-9-phenyl-5-nonene

(2RS,3R,4R,5E,7S)-4-(tert-butyldimethylsilyloxy)-1,2-dihydroxy-3,5,7-trimethyl-9-phenyl-5-nonene

上游原料

(S)-1,1-dibromo-3-methyl-5-phenyl-1-pentene (S)-4-methyl-6-phenyl-2-hexyne di[(E)-1-hexenyl]chloroborane

下游产品

(3R,4R,5E,7S)-1,1-dibromo-3,5,7-trimethyl-4-(t-butyldimethylsilyloxy)-9-phenyl-1,5-nonadiene (1E,3E,7E)-(5R,6R,9S)-1-Iodo-3,5,7,9-tetramethyl-11-phenyl-undeca-1,3,7-trien-6-ol (3Z,5R,6R,7E,9S)-1-trimethylsilyl-3-bromo-5,7,9-trimethyl-6-(t-butyldimethylsilyloxy)-11-phenyl-3,7-undecadien-1-yne (3E,5R,6R,7E,9S)-1-trimethylsilyl-3,5,7,9-tetramethyl-6-(t-butyldimethylsilyloxy)-11-phenyl-3,7-undecadien-1-yne (4R,5R,6E,8S)-4,6,8-trimethyl-5-(t-butyldimethylsilyloxy)-10-phenyl-6-decen-2-yne (3E,5R,6R,7E,9S)-1,1-dibromo-3,5,7,9-tetramethyl-6-(t-butyldimethylsilyloxy)-11-phenyl-1,3,7-undecatriene