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(E)-(4S,5R)-7-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxy-4-methyl-hept-2-enoic acid methyl ester

(E)-(4S,5R)-7-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxy-4-methyl-hept-2-enoic acid methyl ester

CAS号：187218-76-4

英文名：(E)-(4S,5R)-7-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxy-4-methyl-hept-2-enoic acid methyl ester

分子式：C15H30O4Si

分子量：302.482

合成路线

(3R,4S)-1-[(tert-butyldimethylsilyl)oxy]-4-methylhex-5-en-3-ol

(3R,4S)-1-[(tert-butyldimethylsilyl)oxy]-4-methylhex-5-en-3-ol

methyl (triphenylphosphoranylidene)acetate

methyl (triphenylphosphoranylidene)acetate

(E)-(4S,5R)-7-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxy-4-methyl-hept-2-enoic acid methyl ester

(E)-(4S,5R)-7-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxy-4-methyl-hept-2-enoic acid methyl ester

上游原料

(3R,4S)-1-[(tert-butyldimethylsilyl)oxy]-4-methylhex-5-en-3-ol methyl (triphenylphosphoranylidene)acetate

下游产品

tert-Butyl-dimethyl-[2-((2R,3S)-3-methyl-6-methylene-tetrahydro-pyran-2-yl)-ethoxy]-silane 6-[2-(tert-butyldimethylsilanyloxy)ethyl]-5-methyltetrahydropyran-2-one (R)-1-{(2R,5S,7R,8S)-2-Butyl-7-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-8-methyl-1,6-dioxa-spiro[4.5]dec-2-yl}-prop-2-yn-1-ol