百科

(5S,6R,7S,10R)-7-(benzyloxy)-10-ethyl-2,2,3,3,6,14,14-heptamethyl-5-(2-methylallyl)-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecane

(5S,6R,7S,10R)-7-(benzyloxy)-10-ethyl-2,2,3,3,6,14,14-heptamethyl-5-(2-methylallyl)-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecane

CAS号：187862-65-3

英文名：(5S,6R,7S,10R)-7-(benzyloxy)-10-ethyl-2,2,3,3,6,14,14-heptamethyl-5-(2-methylallyl)-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecane

分子式：C43H66O3Si2

分子量：687.153

合成路线

(E)-(R)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-hex-2-enoic acid methyl ester

(E)-(R)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-hex-2-enoic acid methyl ester

(5S,6R,7S,10R)-7-(benzyloxy)-10-ethyl-2,2,3,3,6,14,14-heptamethyl-5-(2-methylallyl)-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecane

(5S,6R,7S,10R)-7-(benzyloxy)-10-ethyl-2,2,3,3,6,14,14-heptamethyl-5-(2-methylallyl)-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecane

(R)-2-[(tert-butyldiphenylsilyloxy)methyl]butan-1-ol

(R)-2-[(tert-butyldiphenylsilyloxy)methyl]butan-1-ol

(5S,6R,7S,10R)-7-(benzyloxy)-10-ethyl-2,2,3,3,6,14,14-heptamethyl-5-(2-methylallyl)-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecane

(5S,6R,7S,10R)-7-(benzyloxy)-10-ethyl-2,2,3,3,6,14,14-heptamethyl-5-(2-methylallyl)-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecane

(E)-(R)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-hex-2-enoic acid methyl ester

(E)-(R)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-hex-2-enoic acid methyl ester

(5S,6R,7S,10R)-7-(benzyloxy)-10-ethyl-2,2,3,3,6,14,14-heptamethyl-5-(2-methylallyl)-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecane

(5S,6R,7S,10R)-7-(benzyloxy)-10-ethyl-2,2,3,3,6,14,14-heptamethyl-5-(2-methylallyl)-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecane

上游原料

(E)-(R)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-hex-2-enoic acid methyl ester (R)-2-[(tert-butyldiphenylsilyloxy)methyl]butan-1-ol (E)-(R)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-hex-2-enoic acid methyl ester

下游产品

(2S,3S,4S,6R,8S,9S)-3,9-dimethyl-8-{(R)-2-[(tert-butyldimethylsilyl)-oxy]-1-propyl}-2-[(R)-3-ethyl-5-(E)-iodo-4-pentenyl]-1,7-dioxaspiro[5.5]undecan-4-ol