百科

4(R)-(4(R)-methoxy-3(R),5(R)-dimethyltetrahydrofuran-2(S)-yl)-2(S)-methylpentane-1,4-diol

4(R)-(4(R)-methoxy-3(R),5(R)-dimethyltetrahydrofuran-2(S)-yl)-2(S)-methylpentane-1,4-diol

CAS号：187962-49-8

英文名：4(R)-(4(R)-methoxy-3(R),5(R)-dimethyltetrahydrofuran-2(S)-yl)-2(S)-methylpentane-1,4-diol

分子式：C13H26O4

分子量：246.343

合成路线

methyl 2-((2R,5S,6S)-6-((S,2E,4E)-7-((2R,3R)-3-((2R,3R,4R)-4-hydroxy-3-methoxypentan-2-yl)-2-methyloxiran-2-yl)-6-methylhepta-2,4-dien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate

methyl 2-((2R,5S,6S)-6-((S,2E,4E)-7-((2R,3R)-3-((2R,3R,4R)-4-hydroxy-3-methoxypentan-2-yl)-2-methyloxiran-2-yl)-6-methylhepta-2,4-dien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate

4(R)-(4(R)-methoxy-3(R),5(R)-dimethyltetrahydrofuran-2(S)-yl)-2(S)-methylpentane-1,4-diol

4(R)-(4(R)-methoxy-3(R),5(R)-dimethyltetrahydrofuran-2(S)-yl)-2(S)-methylpentane-1,4-diol

{(2R,5S,6S)-6-[(1E,3E)-(5S,7S)-7-Hydroxy-7-((2S,3R,4R,5R)-4-methoxy-3,5-dimethyl-tetrahydro-furan-2-yl)-1,5-dimethyl-octa-1,3-dienyl]-5-methyl-tetrahydro-pyran-2-yl}-acetic acid methyl ester

{(2R,5S,6S)-6-[(1E,3E)-(5S,7S)-7-Hydroxy-7-((2S,3R,4R,5R)-4-methoxy-3,5-dimethyl-tetrahydro-furan-2-yl)-1,5-dimethyl-octa-1,3-dienyl]-5-methyl-tetrahydro-pyran-2-yl}-acetic acid methyl ester

4(R)-(4(R)-methoxy-3(R),5(R)-dimethyltetrahydrofuran-2(S)-yl)-2(S)-methylpentane-1,4-diol

4(R)-(4(R)-methoxy-3(R),5(R)-dimethyltetrahydrofuran-2(S)-yl)-2(S)-methylpentane-1,4-diol

{(2R,5S,6S)-5-Methyl-6-[(E)-(5S,7S)-3,4,7-trihydroxy-7-((2S,3R,4R,5R)-4-methoxy-3,5-dimethyl-tetrahydro-furan-2-yl)-1,5-dimethyl-oct-1-enyl]-tetrahydro-pyran-2-yl}-acetic acid methyl ester

{(2R,5S,6S)-5-Methyl-6-[(E)-(5S,7S)-3,4,7-trihydroxy-7-((2S,3R,4R,5R)-4-methoxy-3,5-dimethyl-tetrahydro-furan-2-yl)-1,5-dimethyl-oct-1-enyl]-tetrahydro-pyran-2-yl}-acetic acid methyl ester

4(R)-(4(R)-methoxy-3(R),5(R)-dimethyltetrahydrofuran-2(S)-yl)-2(S)-methylpentane-1,4-diol

4(R)-(4(R)-methoxy-3(R),5(R)-dimethyltetrahydrofuran-2(S)-yl)-2(S)-methylpentane-1,4-diol

上游原料

{(2R,5S,6S)-5-Methyl-6-[(E)-(5S,7S)-3,4,7-trihydroxy-7-((2S,3R,4R,5R)-4-methoxy-3,5-dimethyl-tetrahydro-furan-2-yl)-1,5-dimethyl-oct-1-enyl]-tetrahydro-pyran-2-yl}-acetic acid methyl ester methyl 2-((2R,5S,6S)-6-((S,2E,4E)-7-((2R,3R)-3-((2R,3R,4R)-4-hydroxy-3-methoxypentan-2-yl)-2-methyloxiran-2-yl)-6-methylhepta-2,4-dien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate {(2R,5S,6S)-6-[(1E,3E)-(5S,7S)-7-Hydroxy-7-((2S,3R,4R,5R)-4-methoxy-3,5-dimethyl-tetrahydro-furan-2-yl)-1,5-dimethyl-octa-1,3-dienyl]-5-methyl-tetrahydro-pyran-2-yl}-acetic acid methyl ester

下游产品

5-(tert-butyldimethylsilanyloxy)-4(S)-methylpentan-2-one