百科

(2R,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-hexahydro-pyrano[3,2-b]pyran-3-one

(2R,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-hexahydro-pyrano[3,2-b]pyran-3-one

CAS号：189347-98-6

英文名：(2R,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-hexahydro-pyrano[3,2-b]pyran-3-one

分子式：C43H52O6Si

分子量：692.955

合成路线

(2R,3S,6R)-6-allyl-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-ol

(2R,3S,6R)-6-allyl-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-ol

(2R,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-hexahydro-pyrano[3,2-b]pyran-3-one

(2R,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-hexahydro-pyrano[3,2-b]pyran-3-one

tert-Butyl-[(2S,3R)-2-methyl-3-(toluene-4-sulfonyl)-oxiranylmethoxy]-diphenyl-silane

tert-Butyl-[(2S,3R)-2-methyl-3-(toluene-4-sulfonyl)-oxiranylmethoxy]-diphenyl-silane

(2R,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-hexahydro-pyrano[3,2-b]pyran-3-one

(2R,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-hexahydro-pyrano[3,2-b]pyran-3-one

(2R,4aR,6R,8S,8aS)-6-Allyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

(2R,4aR,6R,8S,8aS)-6-Allyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

(2R,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-hexahydro-pyrano[3,2-b]pyran-3-one

(2R,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-hexahydro-pyrano[3,2-b]pyran-3-one

3-(3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-allopyranosyl)-1-propene

3-(3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-allopyranosyl)-1-propene

(2R,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-hexahydro-pyrano[3,2-b]pyran-3-one

(2R,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-hexahydro-pyrano[3,2-b]pyran-3-one

benzyl 3-(3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-allopyranosyl)propyl ether

benzyl 3-(3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-allopyranosyl)propyl ether

(2R,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-hexahydro-pyrano[3,2-b]pyran-3-one

(2R,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-hexahydro-pyrano[3,2-b]pyran-3-one

上游原料

(2R,4aR,6R,8S,8aS)-6-Allyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol benzyl 3-(3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-allopyranosyl)propyl ether tert-Butyl-[(2S,3R)-2-methyl-3-(toluene-4-sulfonyl)-oxiranylmethoxy]-diphenyl-silane 3-(3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-allopyranosyl)-1-propene (2R,3S,6R)-6-allyl-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-ol

下游产品

(2R,4S,4aS,5aR,8S,9R,10aS,11aR)-4-Benzyloxy-2-(3-benzyloxy-propyl)-9-[(2R,3S)-3-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-2-(toluene-4-sulfonyl)-oxiranylmethyl]-5a-methyl-dodecahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-8-ol