百科

(2R,3S,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-2-triethylsilanyloxymethyl-octahydro-pyrano[3,2-b]pyran

(2R,3S,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-2-triethylsilanyloxymethyl-octahydro-pyrano[3,2-b]pyran

CAS号：189348-20-7

英文名：(2R,3S,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-2-triethylsilanyloxymethyl-octahydro-pyrano[3,2-b]pyran

分子式：C39H64O6Si2

分子量：685.093

合成路线

(2R,3S,6R)-6-allyl-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-ol

(2R,3S,6R)-6-allyl-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-ol

(2R,3S,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-2-triethylsilanyloxymethyl-octahydro-pyrano[3,2-b]pyran

(2R,3S,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-2-triethylsilanyloxymethyl-octahydro-pyrano[3,2-b]pyran

(2R,4aR,6R,8S,8aS)-6-Allyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

(2R,4aR,6R,8S,8aS)-6-Allyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

(2R,3S,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-2-triethylsilanyloxymethyl-octahydro-pyrano[3,2-b]pyran

(2R,3S,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-2-triethylsilanyloxymethyl-octahydro-pyrano[3,2-b]pyran

3-(3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-allopyranosyl)-1-propene

3-(3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-allopyranosyl)-1-propene

(2R,3S,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-2-triethylsilanyloxymethyl-octahydro-pyrano[3,2-b]pyran

(2R,3S,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-2-triethylsilanyloxymethyl-octahydro-pyrano[3,2-b]pyran

benzyl 3-(3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-allopyranosyl)propyl ether

benzyl 3-(3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-allopyranosyl)propyl ether

(2R,3S,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-2-triethylsilanyloxymethyl-octahydro-pyrano[3,2-b]pyran

(2R,3S,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-2-triethylsilanyloxymethyl-octahydro-pyrano[3,2-b]pyran

上游原料

(2R,4aR,6R,8S,8aS)-6-Allyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol benzyl 3-(3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-allopyranosyl)propyl ether 3-(3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-allopyranosyl)-1-propene (2R,3S,6R)-6-allyl-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-ol

下游产品

(2R,4S,4aS,5aR,8S,9R,10aS,11aR)-4-Benzyloxy-2-(3-benzyloxy-propyl)-9-[(2R,3S)-3-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-2-(toluene-4-sulfonyl)-oxiranylmethyl]-5a-methyl-dodecahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-8-ol