百科

(4aR,5R,7S,7aR)-5,7-bis((tert-butyldimethylsilyl)oxy)octahydrocyclopenta[c]pyran-3-ol

(4aR,5R,7S,7aR)-5,7-bis((tert-butyldimethylsilyl)oxy)octahydrocyclopenta[c]pyran-3-ol

CAS号：190390-52-4

英文名：(4aR,5R,7S,7aR)-5,7-bis((tert-butyldimethylsilyl)oxy)octahydrocyclopenta[c]pyran-3-ol

分子式：C20H42O4Si2

分子量：402.716

合成路线

methyl (4R,6S,E)-4,6-bis((tert-butyldimethylsilyl)oxy)-6-((R)-2-thioxo-1,3-dioxolan-4-yl)hex-2-enoate

methyl (4R,6S,E)-4,6-bis((tert-butyldimethylsilyl)oxy)-6-((R)-2-thioxo-1,3-dioxolan-4-yl)hex-2-enoate

(4aR,5R,7S,7aR)-5,7-bis((tert-butyldimethylsilyl)oxy)octahydrocyclopenta[c]pyran-3-ol

(4aR,5R,7S,7aR)-5,7-bis((tert-butyldimethylsilyl)oxy)octahydrocyclopenta[c]pyran-3-ol

上游原料

methyl (4R,6S,E)-4,6-bis((tert-butyldimethylsilyl)oxy)-6-((R)-2-thioxo-1,3-dioxolan-4-yl)hex-2-enoate

下游产品

7-[(1S,2R,3R,5S)-3,5-dihydroxy-2-oct-2-enylcyclopentyl]-5-hydroxyhept-6-enoic acid