百科

(2S,3R,6R)-6-[(R)-5-(2,2-Dimethyl-propionyloxy)-4-hydroxy-pent-1-ynyl]-2-methyl-3-triisopropylsilanyloxy-piperidine-1-carboxylic acid benzyl ester

(2S,3R,6R)-6-[(R)-5-(2,2-Dimethyl-propionyloxy)-4-hydroxy-pent-1-ynyl]-2-methyl-3-triisopropylsilanyloxy-piperidine-1-carboxylic acid benzyl ester

CAS号：191592-77-5

英文名：(2S,3R,6R)-6-[(R)-5-(2,2-Dimethyl-propionyloxy)-4-hydroxy-pent-1-ynyl]-2-methyl-3-triisopropylsilanyloxy-piperidine-1-carboxylic acid benzyl ester

分子式：C33H53NO6Si

分子量：587.863

合成路线

(2S,3R)-2-Methyl-6-trifluoromethanesulfonyloxy-3-triisopropylsilanyloxy-3,4-dihydro-2H-pyridine-1-carboxylic acid benzyl ester

(2S,3R)-2-Methyl-6-trifluoromethanesulfonyloxy-3-triisopropylsilanyloxy-3,4-dihydro-2H-pyridine-1-carboxylic acid benzyl ester

(2S,3R,6R)-6-[(R)-5-(2,2-Dimethyl-propionyloxy)-4-hydroxy-pent-1-ynyl]-2-methyl-3-triisopropylsilanyloxy-piperidine-1-carboxylic acid benzyl ester

(2S,3R,6R)-6-[(R)-5-(2,2-Dimethyl-propionyloxy)-4-hydroxy-pent-1-ynyl]-2-methyl-3-triisopropylsilanyloxy-piperidine-1-carboxylic acid benzyl ester

2,2-Dimethyl-propionic acid (R)-2-hydroxy-pent-4-ynyl ester

2,2-Dimethyl-propionic acid (R)-2-hydroxy-pent-4-ynyl ester

(2S,3R,6R)-6-[(R)-5-(2,2-Dimethyl-propionyloxy)-4-hydroxy-pent-1-ynyl]-2-methyl-3-triisopropylsilanyloxy-piperidine-1-carboxylic acid benzyl ester

(2S,3R,6R)-6-[(R)-5-(2,2-Dimethyl-propionyloxy)-4-hydroxy-pent-1-ynyl]-2-methyl-3-triisopropylsilanyloxy-piperidine-1-carboxylic acid benzyl ester

2,2-dimethylpropionic acid (2R)-2-hydroxy-5-(trimethylsilyl)pent-4-ynyl ester

2,2-dimethylpropionic acid (2R)-2-hydroxy-5-(trimethylsilyl)pent-4-ynyl ester

(2S,3R,6R)-6-[(R)-5-(2,2-Dimethyl-propionyloxy)-4-hydroxy-pent-1-ynyl]-2-methyl-3-triisopropylsilanyloxy-piperidine-1-carboxylic acid benzyl ester

(2S,3R,6R)-6-[(R)-5-(2,2-Dimethyl-propionyloxy)-4-hydroxy-pent-1-ynyl]-2-methyl-3-triisopropylsilanyloxy-piperidine-1-carboxylic acid benzyl ester

(2S,3R)-2-Methyl-6-oxo-3-triisopropylsilanyloxy-piperidine-1-carboxylic acid benzyl ester

(2S,3R)-2-Methyl-6-oxo-3-triisopropylsilanyloxy-piperidine-1-carboxylic acid benzyl ester

(2S,3R,6R)-6-[(R)-5-(2,2-Dimethyl-propionyloxy)-4-hydroxy-pent-1-ynyl]-2-methyl-3-triisopropylsilanyloxy-piperidine-1-carboxylic acid benzyl ester

(2S,3R,6R)-6-[(R)-5-(2,2-Dimethyl-propionyloxy)-4-hydroxy-pent-1-ynyl]-2-methyl-3-triisopropylsilanyloxy-piperidine-1-carboxylic acid benzyl ester

上游原料

(2S,3R)-2-Methyl-6-trifluoromethanesulfonyloxy-3-triisopropylsilanyloxy-3,4-dihydro-2H-pyridine-1-carboxylic acid benzyl ester (2S,3R)-2-Methyl-6-oxo-3-triisopropylsilanyloxy-piperidine-1-carboxylic acid benzyl ester 2,2-Dimethyl-propionic acid (R)-2-hydroxy-pent-4-ynyl ester 2,2-dimethylpropionic acid (2R)-2-hydroxy-5-(trimethylsilyl)pent-4-ynyl ester

下游产品

(E)-1-((4R,6S,7R,9aS)-6-Methyl-7-triisopropylsilanyloxy-octahydro-quinolizin-4-yl)-dec-1-en-4-ol (2S,3R,6S)-6-[(R)-5-Hydroxy-4-(tetrahydro-pyran-2-yloxy)-pentyl]-2-methyl-3-triisopropylsilanyloxy-piperidine-1-carboxylic acid allyl ester (2S,3R,6S)-6-((R)-4-Hydroxy-hex-5-ynyl)-2-methyl-3-triisopropylsilanyloxy-piperidine-1-carboxylic acid allyl ester