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(2R,4S,5R)-4-((Z)-6-Hydroxy-hex-2-enyl)-2-phenyl-[1,3]dioxan-5-ol

(2R,4S,5R)-4-((Z)-6-Hydroxy-hex-2-enyl)-2-phenyl-[1,3]dioxan-5-ol

CAS号：193970-26-2

英文名：(2R,4S,5R)-4-((Z)-6-Hydroxy-hex-2-enyl)-2-phenyl-[1,3]dioxan-5-ol

分子式：C16H22O4

分子量：278.343

合成路线

(2R,4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-4-[(Z)-6-(tert-butyl-dimethyl-silanyloxy)-hex-2-enyl]-2-phenyl-[1,3]dioxane

(2R,4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-4-[(Z)-6-(tert-butyl-dimethyl-silanyloxy)-hex-2-enyl]-2-phenyl-[1,3]dioxane

(2R,4S,5R)-4-((Z)-6-Hydroxy-hex-2-enyl)-2-phenyl-[1,3]dioxan-5-ol

(2R,4S,5R)-4-((Z)-6-Hydroxy-hex-2-enyl)-2-phenyl-[1,3]dioxan-5-ol

(E)-4-[(2R,4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-[1,3]dioxan-4-yl]-but-2-enoic acid methyl ester

(E)-4-[(2R,4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-[1,3]dioxan-4-yl]-but-2-enoic acid methyl ester

(2R,4S,5R)-4-((Z)-6-Hydroxy-hex-2-enyl)-2-phenyl-[1,3]dioxan-5-ol

(2R,4S,5R)-4-((Z)-6-Hydroxy-hex-2-enyl)-2-phenyl-[1,3]dioxan-5-ol

上游原料

(E)-4-[(2R,4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-[1,3]dioxan-4-yl]-but-2-enoic acid methyl ester (2R,4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-4-[(Z)-6-(tert-butyl-dimethyl-silanyloxy)-hex-2-enyl]-2-phenyl-[1,3]dioxane

下游产品

(Z)-(3R,4aS,13aR)-3-Phenyl-4a,5,8,8a,11,13a-hexahydro-1H-2,4,9,10,13-pentaoxa-dibenzo[a,d]cyclononene (Z)-(2R,4aR,6S,7R,11aS)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2-phenyl-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxa-benzocyclononen-7-ol (6Z,9Z)-(2R,4aR,11aS)-2-Phenyl-6-vinyl-4a,8,11,11a-tetrahydro-4H-1,3,5-trioxa-benzocyclononene (Z)-(2R,4aR,11aS)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-eth-(E)-ylidene]-2-phenyl-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxa-benzocyclononen-7-ol (Z)-(2R,4aR,6S,7R,11aS)-6-[(Z)-3-((4aS,6R,10aR)-7,7-Bis-ethylsulfanyl-octahydro-1,5-dioxa-benzocycloocten-6-yl)-allyl]-2-phenyl-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxa-benzocyclononen-7-ol 2,2-Dimethyl-propionic acid (Z)-(2R,4aR,6S,7R,11aS)-6-[(Z)-3-((4aS,6R,10aR)-7,7-bis-ethylsulfanyl-octahydro-1,5-dioxa-benzocycloocten-6-yl)-allyl]-2-phenyl-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxa-benzocyclononen-7-yl ester 2,2-Dimethyl-propionic acid (Z)-(2R,4aR,6S,7R,11aS)-6-(2-iodo-ethyl)-2-phenyl-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxa-benzocyclononen-7-yl ester (Z)-(1S,3R,6R,8S,13R)-15,15-Dimethyl-6-phenyl-2,5,7,14,16-pentaoxa-tricyclo[11.5.0.03,8]octadec-10-ene 2,2-Dimethyl-propionic acid (Z)-(2R,4aR,6S,7R,11aS)-6-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-2-phenyl-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxa-benzocyclononen-7-yl ester (Z)-(2R,4aR,6S,7R,11aS)-6-(2-Hydroxy-ethyl)-2-phenyl-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxa-benzocyclononen-7-ol (Z)-(2R,4aR,6S,11aS)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2-phenyl-4a,8,11,11a-tetrahydro-4H-1,3,5-trioxa-benzocyclononen-7-one (Z)-(2R,4aR,11aS)-6-[2-Hydroxy-eth-(E)-ylidene]-2-phenyl-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxa-benzocyclononen-7-ol (Z)-(2R,4aR,11aS)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-eth-(E)-ylidene]-2-phenyl-4a,8,11,11a-tetrahydro-4H-1,3,5-trioxa-benzocyclononen-7-one 2,2-Dimethyl-propionic acid (Z)-(2R,4aR,6S,7R,11aS)-6-(2-hydroxy-ethyl)-2-phenyl-4a,6,7,8,11,11a-hexahydro-4H-1,3,5-trioxa-benzocyclononen-7-yl ester