百科

(R)-1-((3aS,4R,6R,7S,7aS)-7-Benzyloxy-4-ethylsulfanyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl)-2-(dimethyl-phenyl-silanyl)-ethanol

(R)-1-((3aS,4R,6R,7S,7aS)-7-Benzyloxy-4-ethylsulfanyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl)-2-(dimethyl-phenyl-silanyl)-ethanol

CAS号：195192-37-1

英文名：(R)-1-((3aS,4R,6R,7S,7aS)-7-Benzyloxy-4-ethylsulfanyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl)-2-(dimethyl-phenyl-silanyl)-ethanol

分子式：C27H38O5SSi

分子量：502.738

合成路线

ethyl 1-thio-β-D-glucopyranoside

ethyl 1-thio-β-D-glucopyranoside

(R)-1-((3aS,4R,6R,7S,7aS)-7-Benzyloxy-4-ethylsulfanyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl)-2-(dimethyl-phenyl-silanyl)-ethanol

(R)-1-((3aS,4R,6R,7S,7aS)-7-Benzyloxy-4-ethylsulfanyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl)-2-(dimethyl-phenyl-silanyl)-ethanol

ethyl 2,3-O-isopropylidene-1-thio-6-O-triphenylmethyl-α-D-mannopyranoside

ethyl 2,3-O-isopropylidene-1-thio-6-O-triphenylmethyl-α-D-mannopyranoside

(R)-1-((3aS,4R,6R,7S,7aS)-7-Benzyloxy-4-ethylsulfanyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl)-2-(dimethyl-phenyl-silanyl)-ethanol

(R)-1-((3aS,4R,6R,7S,7aS)-7-Benzyloxy-4-ethylsulfanyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl)-2-(dimethyl-phenyl-silanyl)-ethanol

ethyl 4-O-benzyl-2,3-O-isopropylidene-1-thio-6-O-trityl-α-D-mannopyranoside

ethyl 4-O-benzyl-2,3-O-isopropylidene-1-thio-6-O-trityl-α-D-mannopyranoside

(R)-1-((3aS,4R,6R,7S,7aS)-7-Benzyloxy-4-ethylsulfanyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl)-2-(dimethyl-phenyl-silanyl)-ethanol

(R)-1-((3aS,4R,6R,7S,7aS)-7-Benzyloxy-4-ethylsulfanyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl)-2-(dimethyl-phenyl-silanyl)-ethanol

乙基-2,3,4,6-四-O-乙酰基-α-D-硫代吡喃半乳糖苷

乙基-2,3,4,6-四-O-乙酰基-α-D-硫代吡喃半乳糖苷

(R)-1-((3aS,4R,6R,7S,7aS)-7-Benzyloxy-4-ethylsulfanyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl)-2-(dimethyl-phenyl-silanyl)-ethanol

(R)-1-((3aS,4R,6R,7S,7aS)-7-Benzyloxy-4-ethylsulfanyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl)-2-(dimethyl-phenyl-silanyl)-ethanol

ethyl 4-O-benzyl-2,3-O-isoproylidene-1-thio-α-D-mannopyranoside

ethyl 4-O-benzyl-2,3-O-isoproylidene-1-thio-α-D-mannopyranoside

(R)-1-((3aS,4R,6R,7S,7aS)-7-Benzyloxy-4-ethylsulfanyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl)-2-(dimethyl-phenyl-silanyl)-ethanol

(R)-1-((3aS,4R,6R,7S,7aS)-7-Benzyloxy-4-ethylsulfanyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl)-2-(dimethyl-phenyl-silanyl)-ethanol

上游原料

ethyl 4-O-benzyl-2,3-O-isopropylidene-1-thio-6-O-trityl-α-D-mannopyranoside ethyl 4-O-benzyl-2,3-O-isoproylidene-1-thio-α-D-mannopyranoside ethyl 2,3-O-isopropylidene-1-thio-6-O-triphenylmethyl-α-D-mannopyranoside 乙基-2,3,4,6-四-O-乙酰基-α-D-硫代吡喃半乳糖苷 ethyl 1-thio-β-D-glucopyranoside

下游产品

(2R,3S,4R,5S,6S)-5-Benzyloxy-6-[(R)-1-benzyloxy-2-(dimethyl-phenyl-silanyl)-ethyl]-2-ethylsulfanyl-tetrahydro-pyran-3,4-diol Benzoic acid (2R,3S,4S,5S,6S)-4,5-bis-benzyloxy-6-[(R)-1-benzyloxy-2-(dimethyl-phenyl-silanyl)-ethyl]-2-ethylsulfanyl-tetrahydro-pyran-3-yl ester (2R,3S,4R,5S,6S)-4,5-Bis-benzyloxy-6-[(R)-1-benzyloxy-2-(dimethyl-phenyl-silanyl)-ethyl]-2-ethylsulfanyl-tetrahydro-pyran-3-ol Benzoic acid (2S,3S,4S,5S,6S)-4,5-bis-benzyloxy-6-[(R)-1-benzyloxy-2-(dimethyl-phenyl-silanyl)-ethyl]-2-[(2R,3R,4S,5S,6S)-3,5-bis-benzyloxy-2-((R)-1,2-bis-benzyloxy-ethyl)-6-methoxy-tetrahydro-pyran-4-yloxy]-tetrahydro-pyran-3-yl ester