(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

CAS号：195377-48-1

英文名：(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

分子式：C54H68O10

分子量：877.112

合成路线

(2R,3R,4R,5R,6S,7S,8R)-4-[(benzyloxy)methoxy]-2-hydroxy-8-methoxy-6-methoxymethoxy-3,5,7-trimethyl-9-trityloxynonanoic acid methyl ester

(2R,3R,4R,5R,6S,7S,8R)-4-[(benzyloxy)methoxy]-2-hydroxy-8-methoxy-6-methoxymethoxy-3,5,7-trimethyl-9-trityloxynonanoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(2S,3S,4S)-4-Benzyloxymethoxy-5-(tert-butyl-diphenyl-silanyloxy)-2-methoxymethoxy-3-methyl-pentan-1-ol

(2S,3S,4S)-4-Benzyloxymethoxy-5-(tert-butyl-diphenyl-silanyloxy)-2-methoxymethoxy-3-methyl-pentan-1-ol

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(2S,3R,4S)-4-[(benzyloxy)methoxy]-5-(tert-butyldiphenylsilanyloxy)-2-methoxymethoxy-3-methylpentanoic acid methyl ester

(2S,3R,4S)-4-[(benzyloxy)methoxy]-5-(tert-butyldiphenylsilanyloxy)-2-methoxymethoxy-3-methylpentanoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(4R,5S,6S)-6-[(benzyloxy)methoxy]-7-(tert-butyldiphenylsilanyloxy)-4-methoxymethoxy-5-methylhept-2-enoic acid methyl ester

(4R,5S,6S)-6-[(benzyloxy)methoxy]-7-(tert-butyldiphenylsilanyloxy)-4-methoxymethoxy-5-methylhept-2-enoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(3R,4R,5S,6S)-6-[(benzyloxy)methoxy]-7-(tert-butyldiphenylsilanyloxy)-4-methoxymethoxy-3,5-dimethylheptanoic acid methyl ester

(3R,4R,5S,6S)-6-[(benzyloxy)methoxy]-7-(tert-butyldiphenylsilanyloxy)-4-methoxymethoxy-3,5-dimethylheptanoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(2R,3R,4R,5S,6S)-6-[(benzyloxy)methoxy]-7-(tert-butyldiphenylsilanyloxy)-2-hydroxy-4-methoxymethoxy-3,5-dimethylheptanoic acid methyl ester

(2R,3R,4R,5S,6S)-6-[(benzyloxy)methoxy]-7-(tert-butyldiphenylsilanyloxy)-2-hydroxy-4-methoxymethoxy-3,5-dimethylheptanoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(4R,5R,6S,7S,8R)-4-[(benzyloxy)methoxy]-8-methoxy-6-methoxymethoxy-5,7-dimethyl-9-trityloxynon-2-enoic acid methyl ester

(4R,5R,6S,7S,8R)-4-[(benzyloxy)methoxy]-8-methoxy-6-methoxymethoxy-5,7-dimethyl-9-trityloxynon-2-enoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(3R,4R,5R,6S,7S,8R)-4-[(benzyloxy)methoxy]-8-methoxy-6-methoxymethoxy-3,5,7-trimethyl-9-trityloxynonanoic acid methyl ester

(3R,4R,5R,6S,7S,8R)-4-[(benzyloxy)methoxy]-8-methoxy-6-methoxymethoxy-3,5,7-trimethyl-9-trityloxynonanoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(2R,3S,4S,5S,6S,7S,8R)-2,4-Bis-benzyloxymethoxy-8-methoxy-6-methoxymethoxy-3,5,7-trimethyl-9-trityloxy-nonanoic acid methyl ester

(2R,3S,4S,5S,6S,7S,8R)-2,4-Bis-benzyloxymethoxy-8-methoxy-6-methoxymethoxy-3,5,7-trimethyl-9-trityloxy-nonanoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(2R,3R,4R,5S,6S)-6-Benzyloxymethoxy-7-(tert-butyl-diphenyl-silanyloxy)-4-methoxymethoxy-3,5-dimethyl-1-trityloxy-heptan-2-ol

(2R,3R,4R,5S,6S)-6-Benzyloxymethoxy-7-(tert-butyl-diphenyl-silanyloxy)-4-methoxymethoxy-3,5-dimethyl-1-trityloxy-heptan-2-ol

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

(3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester

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上游原料

(2R,3S,4R,5S,6S)-6-[(benzyloxy)methoxy]-7-(tert-butyldiphenylsilanyloxy)-2-methoxy-4-methoxymethoxy-3,5-dimethyl-1-trityloxyheptane (2S,3S,4R,5S,6R)-2-Benzyloxymethoxy-6-methoxy-4-methoxymethoxy-3,5-dimethyl-7-trityloxy-heptan-1-ol (3R,4R,5R,6S,7S,8R)-4-[(benzyloxy)methoxy]-8-methoxy-6-methoxymethoxy-3,5,7-trimethyl-9-trityloxynonanoic acid methyl ester (2R,3R,4R,5S,6S)-6-Benzyloxymethoxy-7-(tert-butyl-diphenyl-silanyloxy)-4-methoxymethoxy-3,5-dimethyl-heptane-1,2-diol (4R,5R,6S,7S,8R)-4-[(benzyloxy)methoxy]-8-methoxy-6-methoxymethoxy-5,7-dimethyl-9-trityloxynon-2-enoic acid methyl ester (2S,3S,4S)-4-Benzyloxymethoxy-5-(tert-butyl-diphenyl-silanyloxy)-2-methoxymethoxy-3-methyl-pentan-1-ol (2R,3S,4S,5S,6S,7S,8R)-2,4-Bis-benzyloxymethoxy-8-methoxy-6-methoxymethoxy-3,5,7-trimethyl-9-trityloxy-nonanoic acid methyl ester (2S,3S,4S)-4-[(benzyloxy)methoxy]-5-(tert-butyldiphenylsilanyloxy)-2-hydroxy-3-methylpentanoic acid methyl ester (3R,4R,5S,6S)-6-[(benzyloxy)methoxy]-7-(tert-butyldiphenylsilanyloxy)-4-methoxymethoxy-3,5-dimethylheptanoic acid methyl ester (2R,3R,4R,5R,6S,7S,8R)-4-[(benzyloxy)methoxy]-2-hydroxy-8-methoxy-6-methoxymethoxy-3,5,7-trimethyl-9-trityloxynonanoic acid methyl ester (2R,3R,4R,5S,6S)-6-[(benzyloxy)methoxy]-7-(tert-butyldiphenylsilanyloxy)-2-hydroxy-4-methoxymethoxy-3,5-dimethylheptanoic acid methyl ester (2R,3R,4R,5S,6S)-6-Benzyloxymethoxy-7-(tert-butyl-diphenyl-silanyloxy)-4-methoxymethoxy-3,5-dimethyl-1-trityloxy-heptan-2-ol (4R,5S,6S)-6-[(benzyloxy)methoxy]-7-(tert-butyldiphenylsilanyloxy)-4-methoxymethoxy-5-methylhept-2-enoic acid methyl ester (2S,3R,4S)-4-[(benzyloxy)methoxy]-5-(tert-butyldiphenylsilanyloxy)-2-methoxymethoxy-3-methylpentanoic acid methyl ester

下游产品

(2S,3S,4S,5R,6R,7R,8S,9S,10R)-4,6-bis-[(benzyloxy)methoxy]-2-hydroxy-10-methoxy-8-methoxymethoxy-3,5,7,9-tetramethyl-11-trityloxyundecanoic acid methyl ester