百科

(2S,3R,4S,5R,6R)-2-[(3R,4R,5R,6S)-4,5-Dihydroxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yloxy]-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol

(2S,3R,4S,5R,6R)-2-[(3R,4R,5R,6S)-4,5-Dihydroxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yloxy]-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol

CAS号：197143-85-4

英文名：(2S,3R,4S,5R,6R)-2-[(3R,4R,5R,6S)-4,5-Dihydroxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yloxy]-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol

分子式：C16H32O10Si

分子量：412.505

合成路线

2'-trimethylsilylethyl β-D-xylopyranoside

2'-trimethylsilylethyl β-D-xylopyranoside

(2S,3R,4S,5R,6R)-2-[(3R,4R,5R,6S)-4,5-Dihydroxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yloxy]-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol

(2S,3R,4S,5R,6R)-2-[(3R,4R,5R,6S)-4,5-Dihydroxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yloxy]-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol

Acetic acid (2S,3R,4S,5R)-4,5-diacetoxy-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester

Acetic acid (2S,3R,4S,5R)-4,5-diacetoxy-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester

(2S,3R,4S,5R,6R)-2-[(3R,4R,5R,6S)-4,5-Dihydroxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yloxy]-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol

(2S,3R,4S,5R,6R)-2-[(3R,4R,5R,6S)-4,5-Dihydroxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yloxy]-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol

(2S,3R,4R,5R)-5-(tert-Butyl-diphenyl-silanyloxy)-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3,4-diol

(2S,3R,4R,5R)-5-(tert-Butyl-diphenyl-silanyloxy)-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3,4-diol

(2S,3R,4S,5R,6R)-2-[(3R,4R,5R,6S)-4,5-Dihydroxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yloxy]-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol

(2S,3R,4S,5R,6R)-2-[(3R,4R,5R,6S)-4,5-Dihydroxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yloxy]-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol

上游原料

Acetic acid (2S,3R,4S,5R)-4,5-diacetoxy-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester (2S,3R,4R,5R)-5-(tert-Butyl-diphenyl-silanyloxy)-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3,4-diol 2'-trimethylsilylethyl β-D-xylopyranoside

下游产品

2-(trimethylsilyl)ethyl (2,6-di-O-acetyl-β-D-galactopyranosyl)-(1->4)-2,3-di-O-acetyl-β-D-xylopyranoside Acetic acid (3aS,4R,6S,7R,7aS)-4-acetoxymethyl-6-[(3R,4S,5R,6S)-4,5-diacetoxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yloxy]-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester