百科

(2''S,3''S)-3-O-[2',6'-di-O-benzyl-3',4'-di-O-(2'',3''-dimethoxybutane-2'',3''-diyl)-α-D-glucopyranosyl]-1,2-O-isopropylidene-5-O-tert-butyldiphenylsilyl-α-D-ribofuranoside

(2''S,3''S)-3-O-[2',6'-di-O-benzyl-3',4'-di-O-(2'',3''-dimethoxybutane-2'',3''-diyl)-α-D-glucopyranosyl]-1,2-O-isopropylidene-5-O-tert-butyldiphenylsilyl-α-D-ribofuranoside

CAS号：197644-81-8

英文名：(2''S,3''S)-3-O-[2',6'-di-O-benzyl-3',4'-di-O-(2'',3''-dimethoxybutane-2'',3''-diyl)-α-D-glucopyranosyl]-1,2-O-isopropylidene-5-O-tert-butyldiphenylsilyl-α-D-ribofuranoside

分子式：C50H64O12Si

分子量：885.121

合成路线

乙基-2,3,4,6-四-O-乙酰基-α-D-硫代吡喃半乳糖苷

乙基-2,3,4,6-四-O-乙酰基-α-D-硫代吡喃半乳糖苷

(2''S,3''S)-3-O-[2',6'-di-O-benzyl-3',4'-di-O-(2'',3''-dimethoxybutane-2'',3''-diyl)-α-D-glucopyranosyl]-1,2-O-isopropylidene-5-O-tert-butyldiphenylsilyl-α-D-ribofuranoside

(2''S,3''S)-3-O-[2',6'-di-O-benzyl-3',4'-di-O-(2'',3''-dimethoxybutane-2'',3''-diyl)-α-D-glucopyranosyl]-1,2-O-isopropylidene-5-O-tert-butyldiphenylsilyl-α-D-ribofuranoside

上游原料

乙基-2,3,4,6-四-O-乙酰基-α-D-硫代吡喃半乳糖苷

下游产品

5-azido-5-deoxy-3-O-{2,6-di-O-benzyl-3,4-di-O-[(2'S,3'S)-2',3'-dimethoxybutane-2',3'-diyl]-α-D-glucopyranosyl}-1,2-O-isopropylidene-α-D-ribofuranoside 5'-azido-N6-benzoyl-3'-O-(2'',6''-di-O-benzyl-α-D-glucopyranosyl)-5'-deoxyadenosine 1,2-di-O-acetyl-3-O-(3',4'-di-O-acetyl-2',6'-di-O-benzyl-α-D-glucopyranosyl)-5-O-benzyl-α/β-D-ribofuranoside 2'-O-acetyl-3'-O-(3'',4''-di-O-acetyl-2'',6''-di-O-benzyl-α-D-glucopyranosyl)-5'-azido-N6-benzoyl-5'-deoxyadenosine