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(Z)-(4S,5S)-5,6-Dihydroxy-4-(4-methoxy-benzyloxy)-hex-2-enoic acid methyl ester

(Z)-(4S,5S)-5,6-Dihydroxy-4-(4-methoxy-benzyloxy)-hex-2-enoic acid methyl ester

CAS号：198057-22-6

英文名：(Z)-(4S,5S)-5,6-Dihydroxy-4-(4-methoxy-benzyloxy)-hex-2-enoic acid methyl ester

分子式：C15H20O6

分子量：296.316

合成路线

(S)-4-((S)-2,2-Diethyl-[1,3]dioxolan-4-yl)-4-(4-methoxy-benzyloxy)-but-2-ynoic acid methyl ester

(S)-4-((S)-2,2-Diethyl-[1,3]dioxolan-4-yl)-4-(4-methoxy-benzyloxy)-but-2-ynoic acid methyl ester

(Z)-(4S,5S)-5,6-Dihydroxy-4-(4-methoxy-benzyloxy)-hex-2-enoic acid methyl ester

(Z)-(4S,5S)-5,6-Dihydroxy-4-(4-methoxy-benzyloxy)-hex-2-enoic acid methyl ester

(3S,4S)-1,1-dibromo-3-(4-methoxybenzyloxy)-4,5-pentylidenedioxy-1-pentene

(3S,4S)-1,1-dibromo-3-(4-methoxybenzyloxy)-4,5-pentylidenedioxy-1-pentene

(Z)-(4S,5S)-5,6-Dihydroxy-4-(4-methoxy-benzyloxy)-hex-2-enoic acid methyl ester

(Z)-(4S,5S)-5,6-Dihydroxy-4-(4-methoxy-benzyloxy)-hex-2-enoic acid methyl ester

上游原料

(S)-4-((S)-2,2-Diethyl-[1,3]dioxolan-4-yl)-4-(4-methoxy-benzyloxy)-but-2-ynoic acid methyl ester (3S,4S)-1,1-dibromo-3-(4-methoxybenzyloxy)-4,5-pentylidenedioxy-1-pentene

下游产品

(1R,2R,4S,5R,6R)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-methoxy-3,7-dioxa-bicyclo[4.1.0]heptan-5-ol (5S,6S)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-5-(4-methoxy-benzyloxy)-5,6-dihydro-pyran-2-one tert-Butyl-[(2S,3S,6R)-6-methoxy-3-(4-methoxy-benzyloxy)-3,6-dihydro-2H-pyran-2-ylmethoxy]-diphenyl-silane