百科

(3aR,5S,7R,7aR)-7-(tert-Butyl-diphenyl-silanyloxy)-2,2-dimethyl-5-[2-methyl-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-propoxymethyl]-hexahydro-benzo[1,3]dioxol-5-ol

CAS号：198469-40-8

英文名：(3aR,5S,7R,7aR)-7-(tert-Butyl-diphenyl-silanyloxy)-2,2-dimethyl-5-[2-methyl-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-propoxymethyl]-hexahydro-benzo[1,3]dioxol-5-ol

分子式：C57H72O10Si

分子量：945.261

合成路线

160776-15-8

2,3,4-tri-O-benzyl-β-L-fucopyranosyl 2-thiopyridyl carbonate

198469-39-5

(3aR,5S,7R,7aR)-7-(tert-Butyl-diphenyl-silanyloxy)-5-(2-hydroxy-2-methyl-propoxymethyl)-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-5-ol

198469-40-8

(3aR,5S,7R,7aR)-7-(tert-Butyl-diphenyl-silanyloxy)-2,2-dimethyl-5-[2-methyl-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-propoxymethyl]-hexahydro-benzo[1,3]dioxol-5-ol

198469-37-3

(3aR,5S,7R,7aR)-7-(tert-Butyl-diphenyl-silanyloxy)-5-hydroxymethyl-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-5-ol

198469-40-8

(3aR,5S,7R,7aR)-7-(tert-Butyl-diphenyl-silanyloxy)-2,2-dimethyl-5-[2-methyl-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-propoxymethyl]-hexahydro-benzo[1,3]dioxol-5-ol

130474-38-3

3,4-isopropylidenequinide

198469-40-8

(3aR,5S,7R,7aR)-7-(tert-Butyl-diphenyl-silanyloxy)-2,2-dimethyl-5-[2-methyl-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-propoxymethyl]-hexahydro-benzo[1,3]dioxol-5-ol

198469-38-4

(3aR,5S,7R,7aR)-7-(tert-Butyl-diphenyl-silanyloxy)-2,2-dimethyl-5-(2-methyl-allyloxymethyl)-hexahydro-benzo[1,3]dioxol-5-ol

198469-40-8

(3aR,5S,7R,7aR)-7-(tert-Butyl-diphenyl-silanyloxy)-2,2-dimethyl-5-[2-methyl-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-propoxymethyl]-hexahydro-benzo[1,3]dioxol-5-ol

198469-42-0

methyl (-)-3,4-O-isopropylidene-5-O-(tert-butyldiphenylsilyl)quinate

198469-40-8

(3aR,5S,7R,7aR)-7-(tert-Butyl-diphenyl-silanyloxy)-2,2-dimethyl-5-[2-methyl-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-propoxymethyl]-hexahydro-benzo[1,3]dioxol-5-ol

上游原料

2,3,4-tri-O-benzyl-β-L-fucopyranosyl 2-thiopyridyl carbonate (3aR,5S,7R,7aR)-7-(tert-Butyl-diphenyl-silanyloxy)-5-(2-hydroxy-2-methyl-propoxymethyl)-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-5-ol methyl (-)-3,4-O-isopropylidene-5-O-(tert-butyldiphenylsilyl)quinate 3,4-isopropylidenequinide (3aR,5S,7R,7aR)-7-(tert-Butyl-diphenyl-silanyloxy)-5-hydroxymethyl-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-5-ol (3aR,5S,7R,7aR)-7-(tert-Butyl-diphenyl-silanyloxy)-2,2-dimethyl-5-(2-methyl-allyloxymethyl)-hexahydro-benzo[1,3]dioxol-5-ol

下游产品

(4aR,5R,7S,8aR)-5-(tert-Butyl-diphenyl-silanyloxy)-7-hydroxy-7-[2-methyl-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-propoxymethyl]-hexahydro-benzo[1,4]dioxin-2-one