百科

(3aS,6R,7S,7aR)-2,2-Dimethyl-7-(tetrahydro-pyran-2-yloxy)-5-(toluene-4-sulfonyl)-hexahydro-[1,3]dioxolo[4,5-c]pyridine-6-carboxylic acid benzyl ester

(3aS,6R,7S,7aR)-2,2-Dimethyl-7-(tetrahydro-pyran-2-yloxy)-5-(toluene-4-sulfonyl)-hexahydro-[1,3]dioxolo[4,5-c]pyridine-6-carboxylic acid benzyl ester

CAS号：198565-93-4

英文名：(3aS,6R,7S,7aR)-2,2-Dimethyl-7-(tetrahydro-pyran-2-yloxy)-5-(toluene-4-sulfonyl)-hexahydro-[1,3]dioxolo[4,5-c]pyridine-6-carboxylic acid benzyl ester

分子式：C28H35NO8S

分子量：545.644

合成路线

(4R,5S)-5-tert-butyldimethylsilyloxymethyl-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde

(4R,5S)-5-tert-butyldimethylsilyloxymethyl-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde

(3aS,6R,7S,7aR)-2,2-Dimethyl-7-(tetrahydro-pyran-2-yloxy)-5-(toluene-4-sulfonyl)-hexahydro-[1,3]dioxolo[4,5-c]pyridine-6-carboxylic acid benzyl ester

(3aS,6R,7S,7aR)-2,2-Dimethyl-7-(tetrahydro-pyran-2-yloxy)-5-(toluene-4-sulfonyl)-hexahydro-[1,3]dioxolo[4,5-c]pyridine-6-carboxylic acid benzyl ester

(S)-3-[(4S,5S)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-3-hydroxy-2-(toluene-4-sulfonylamino)-propionic acid benzyl ester

(S)-3-[(4S,5S)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-3-hydroxy-2-(toluene-4-sulfonylamino)-propionic acid benzyl ester

(3aS,6R,7S,7aR)-2,2-Dimethyl-7-(tetrahydro-pyran-2-yloxy)-5-(toluene-4-sulfonyl)-hexahydro-[1,3]dioxolo[4,5-c]pyridine-6-carboxylic acid benzyl ester

(3aS,6R,7S,7aR)-2,2-Dimethyl-7-(tetrahydro-pyran-2-yloxy)-5-(toluene-4-sulfonyl)-hexahydro-[1,3]dioxolo[4,5-c]pyridine-6-carboxylic acid benzyl ester

(S)-3-[(4S,5S)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-3-(tetrahydro-pyran-2-yloxy)-2-(toluene-4-sulfonylamino)-propionic acid benzyl ester

(S)-3-[(4S,5S)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-3-(tetrahydro-pyran-2-yloxy)-2-(toluene-4-sulfonylamino)-propionic acid benzyl ester

(3aS,6R,7S,7aR)-2,2-Dimethyl-7-(tetrahydro-pyran-2-yloxy)-5-(toluene-4-sulfonyl)-hexahydro-[1,3]dioxolo[4,5-c]pyridine-6-carboxylic acid benzyl ester

(3aS,6R,7S,7aR)-2,2-Dimethyl-7-(tetrahydro-pyran-2-yloxy)-5-(toluene-4-sulfonyl)-hexahydro-[1,3]dioxolo[4,5-c]pyridine-6-carboxylic acid benzyl ester

上游原料

(4R,5S)-5-tert-butyldimethylsilyloxymethyl-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde (S)-3-[(4S,5S)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-3-hydroxy-2-(toluene-4-sulfonylamino)-propionic acid benzyl ester (S)-3-[(4S,5S)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-3-(tetrahydro-pyran-2-yloxy)-2-(toluene-4-sulfonylamino)-propionic acid benzyl ester

下游产品

[(3aS,6S,7S,7aR)-2,2-Dimethyl-7-(tetrahydro-pyran-2-yloxy)-hexahydro-[1,3]dioxolo[4,5-c]pyridin-6-yl]-methanol