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(22R)-5,6beta,22,27-四羟基-1-氧代-5alpha-麦角甾-2,24-二烯-26-酸 gamma-内酯

(22R)-5,6beta,22,27-四羟基-1-氧代-5alpha-麦角甾-2,24-二烯-26-酸 gamma-内酯

CAS号：19891-82-8

英文名：Jaborosalactone D

分子式

C28H40O6

熔点

密度

1.235g/cm3

分子量

472.614

沸点

656.6ºC at 760 mmHg

溶解度

信号词

危险品标志

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基本信息

中文名称

(22R)-5,6beta,22,27-四羟基-1-氧代-5alpha-麦角甾-2,24-二烯-26-酸 gamma-内酯

英文名称

Jaborosalactone D

中文别名

英文别名

CAS号

19891-82-8

分子式

C28H40O6

分子量

472.614

精确质量

472.282

PSA

104.06

LOGP

3.3365

物化性质

密度

1.235g/cm3

沸点

656.6ºC at 760 mmHg

闪点

215.5ºC

折射率

1.578

蒸汽压

5E-20mmHg at 25°C

合成路线

(R)-6-((S)-1-((1S,3R,8S,9S,10R,13S,14S,17R)-1,3-bis(methoxymethoxy)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)ethyl)-4-methyl-5,6-dihydro-2H-pyran-2-one

(R)-6-((S)-1-((1S,3R,8S,9S,10R,13S,14S,17R)-1,3-bis(methoxymethoxy)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)ethyl)-4-methyl-5,6-dihydro-2H-pyran-2-one

(22R)-5,6beta,22,27-四羟基-1-氧代-5alpha-麦角甾-2,24-二烯-26-酸 gamma-内酯

(22R)-5,6beta,22,27-四羟基-1-氧代-5alpha-麦角甾-2,24-二烯-26-酸 gamma-内酯

上游原料

共找到3个上游原料 >

(3R,4R,6R)-6-((S)-1-((1S,3R,8S,9S,10R,13S,14S,17R)-1,3-bis(methoxymethoxy)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)ethyl)-3-(hydroxymethyl)-4-methyl-3-(phenylthio)tetrahydro-2H-pyran-2-one

(3R,4R,6R)-6-((S)-1-((1S,3R,8S,9S,10R,13S,14S,17R)-1,3-bis(methoxymethoxy)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)ethyl)-3-(hydroxymethyl)-4-methyl-3-(phenylthio)tetrahydro-2H-pyran-2-one

(R)-6-((S)-1-((1S,3R,8S,9S,10R,13S,14S,17R)-1,3-bis(methoxymethoxy)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)ethyl)-4-methyl-5,6-dihydro-2H-pyran-2-one

(R)-6-((S)-1-((1S,3R,8S,9S,10R,13S,14S,17R)-1,3-bis(methoxymethoxy)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)ethyl)-4-methyl-5,6-dihydro-2H-pyran-2-one

(4R,6R)-6-((1S)-1-((1S,3R,8S,9S,10R,13S,14S)-1,3-bis(methoxymethoxy)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)ethyl)-4-methyl-3-(phenylthio)tetrahydro-2H-pyran-2-one

(4R,6R)-6-((1S)-1-((1S,3R,8S,9S,10R,13S,14S)-1,3-bis(methoxymethoxy)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)ethyl)-4-methyl-3-(phenylthio)tetrahydro-2H-pyran-2-one

上游原料

(3R,4R,6R)-6-((S)-1-((1S,3R,8S,9S,10R,13S,14S,17R)-1,3-bis(methoxymethoxy)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)ethyl)-3-(hydroxymethyl)-4-methyl-3-(phenylthio)tetrahydro-2H-pyran-2-one (R)-6-((S)-1-((1S,3R,8S,9S,10R,13S,14S,17R)-1,3-bis(methoxymethoxy)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)ethyl)-4-methyl-5,6-dihydro-2H-pyran-2-one (4R,6R)-6-((1S)-1-((1S,3R,8S,9S,10R,13S,14S)-1,3-bis(methoxymethoxy)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)ethyl)-4-methyl-3-(phenylthio)tetrahydro-2H-pyran-2-one