百科

(1S,4aS,5R,6R)-(-)-1,2,3,4,4a,5,6,7-octahydro-5-[2-keto-2-(3-furyl)ethyl]-1-(4-methyl-4-pentenyl)-1,5,6-trimethylnaphthalene

(1S,4aS,5R,6R)-(-)-1,2,3,4,4a,5,6,7-octahydro-5-[2-keto-2-(3-furyl)ethyl]-1-(4-methyl-4-pentenyl)-1,5,6-trimethylnaphthalene

CAS号：199525-18-3

英文名：(1S,4aS,5R,6R)-(-)-1,2,3,4,4a,5,6,7-octahydro-5-[2-keto-2-(3-furyl)ethyl]-1-(4-methyl-4-pentenyl)-1,5,6-trimethylnaphthalene

分子式：C25H36O2

分子量：368.552

合成路线

(4aS,5S,8S,8aS)-(+)-3,4,4a,5,6,7,8,8a-octahydro-5-(2-hydroxyethyl)-6-methenyl-5,8a-dimethyl-8-trimethylsilylnaphthalen-1(2H)-one 1-(ethylene acetal)

(4aS,5S,8S,8aS)-(+)-3,4,4a,5,6,7,8,8a-octahydro-5-(2-hydroxyethyl)-6-methenyl-5,8a-dimethyl-8-trimethylsilylnaphthalen-1(2H)-one 1-(ethylene acetal)

(1S,4aS,5R,6R)-(-)-1,2,3,4,4a,5,6,7-octahydro-5-[2-keto-2-(3-furyl)ethyl]-1-(4-methyl-4-pentenyl)-1,5,6-trimethylnaphthalene

(1S,4aS,5R,6R)-(-)-1,2,3,4,4a,5,6,7-octahydro-5-[2-keto-2-(3-furyl)ethyl]-1-(4-methyl-4-pentenyl)-1,5,6-trimethylnaphthalene

(4aS)-1,4aβ-dimethyl-4,4a,7,8-tetrahydronaphthalene-2,5(3H,6H)-dione-5-ethyeneacetal

(4aS)-1,4aβ-dimethyl-4,4a,7,8-tetrahydronaphthalene-2,5(3H,6H)-dione-5-ethyeneacetal

(1S,4aS,5R,6R)-(-)-1,2,3,4,4a,5,6,7-octahydro-5-[2-keto-2-(3-furyl)ethyl]-1-(4-methyl-4-pentenyl)-1,5,6-trimethylnaphthalene

(1S,4aS,5R,6R)-(-)-1,2,3,4,4a,5,6,7-octahydro-5-[2-keto-2-(3-furyl)ethyl]-1-(4-methyl-4-pentenyl)-1,5,6-trimethylnaphthalene

(1S,4aS,5R,6R,8S,8aS)-1-Allyl-5-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-5,6,8a-trimethyl-8-trimethylsilanyl-decahydro-naphthalen-1-ol

(1S,4aS,5R,6R,8S,8aS)-1-Allyl-5-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-5,6,8a-trimethyl-8-trimethylsilanyl-decahydro-naphthalen-1-ol

(1S,4aS,5R,6R)-(-)-1,2,3,4,4a,5,6,7-octahydro-5-[2-keto-2-(3-furyl)ethyl]-1-(4-methyl-4-pentenyl)-1,5,6-trimethylnaphthalene

(1S,4aS,5R,6R)-(-)-1,2,3,4,4a,5,6,7-octahydro-5-[2-keto-2-(3-furyl)ethyl]-1-(4-methyl-4-pentenyl)-1,5,6-trimethylnaphthalene

上游原料

(4aS)-1,4aβ-dimethyl-4,4a,7,8-tetrahydronaphthalene-2,5(3H,6H)-dione-5-ethyeneacetal (1S,4aS,5R,6R,8S,8aS)-1-Allyl-5-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-5,6,8a-trimethyl-8-trimethylsilanyl-decahydro-naphthalen-1-ol (4aS,5S,8S,8aS)-(+)-3,4,4a,5,6,7,8,8a-octahydro-5-(2-hydroxyethyl)-6-methenyl-5,8a-dimethyl-8-trimethylsilylnaphthalen-1(2H)-one 1-(ethylene acetal)

下游产品

(1S,4aS,5R,6R)-(-)-1,2,3,4,4a,5,6,7-octahydro-5-[2R-2-hydroxy-2-(3-furyl)ethyl]-1-(4-methyl-4-pentenyl)-1,5,6-trimethylnaphthalene