百科

(4E,8E,12E)-14-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-4,8,12-trimethyl-tetradeca-4,8,12-trienoic acid methyl ester

(4E,8E,12E)-14-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-4,8,12-trimethyl-tetradeca-4,8,12-trienoic acid methyl ester

CAS号：201004-66-2

英文名：(4E,8E,12E)-14-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-4,8,12-trimethyl-tetradeca-4,8,12-trienoic acid methyl ester

分子式：C37H60O6Si

分子量：628.954

合成路线

(2E,6E,10E)-13-(3,3-dimethyloxiran-2-yl)-3,7,11-trimethyltrideca-2,6,10-trien-1-ol

(2E,6E,10E)-13-(3,3-dimethyloxiran-2-yl)-3,7,11-trimethyltrideca-2,6,10-trien-1-ol

(4E,8E,12E)-14-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-4,8,12-trimethyl-tetradeca-4,8,12-trienoic acid methyl ester

(4E,8E,12E)-14-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-4,8,12-trimethyl-tetradeca-4,8,12-trienoic acid methyl ester

geranylgeranyl acetate

geranylgeranyl acetate

(4E,8E,12E)-14-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-4,8,12-trimethyl-tetradeca-4,8,12-trienoic acid methyl ester

(4E,8E,12E)-14-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-4,8,12-trimethyl-tetradeca-4,8,12-trienoic acid methyl ester

上游原料

geranylgeranyl acetate (2E,6E,10E)-13-(3,3-dimethyloxiran-2-yl)-3,7,11-trimethyltrideca-2,6,10-trien-1-ol

下游产品

(4E,8E,12E,16Z)-18-[2-Acetoxy-3,4-dimethyl-5-(tetrahydro-pyran-2-yloxy)-phenyl]-4,8,12,16-tetramethyl-octadeca-4,8,12,16-tetraenoic acid ethyl ester (4E,8E,12E,16Z)-18-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-4,8,12,16-tetramethyl-octadeca-4,8,12,16-tetraenoic acid ethyl ester (4E,8E,12E)-14-(2-Acetoxy-5-hydroxy-3,4-dimethyl-phenyl)-4,8,12-trimethyl-tetradeca-4,8,12-trienoic acid methyl ester (4E,8E,12E,16Z)-18-[2-Hydroxy-3,4-dimethyl-5-(tetrahydro-pyran-2-yloxy)-phenyl]-4,8,12,16-tetramethyl-octadeca-4,8,12,16-tetraenoic acid ethyl ester 14-(2-Acetoxy-5-hydroxy-3,4-dimethyl-phenyl)-4,8,12-trimethyl-tetradecanoic acid methyl ester (4E,8E,12Z)-14-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-4,8,12-trimethyl-tetradeca-4,8,12-trienal (4E,8E,12Z)-14-(2-Acetoxy-5-hydroxy-3,4-dimethyl-phenyl)-4,8,12-trimethyl-tetradeca-4,8,12-trienoic acid methyl ester (4E,8E,12E)-14-(5-Hydroxy-2,3,4-trimethyl-phenyl)-4,8,12-trimethyl-tetradeca-4,8,12-trienoic acid methyl ester (4E,8E,12E)-14-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-4,8,12-trimethyl-tetradeca-4,8,12-trien-1-ol 14-[2-Acetoxy-3,4-dimethyl-5-((2S,3R,4S,5R)-3,4,5-triacetoxy-tetrahydro-pyran-2-yloxy)-phenyl]-4,8,12-trimethyl-tetradecanoic acid methyl ester (4E,8E,12E)-14-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-trifluoromethanesulfonyloxy-phenyl]-4,8,12-trimethyl-tetradeca-4,8,12-trienoic acid methyl ester (4E,8E,12E)-4,8,12-Trimethyl-14-[2,3,4-trimethyl-5-(tetrahydro-pyran-2-yloxy)-phenyl]-tetradeca-4,8,12-trienoic acid methyl ester (4E,8E,12E,16Z)-18-(2-Acetoxy-5-hydroxy-3,4-dimethyl-phenyl)-4,8,12,16-tetramethyl-octadeca-4,8,12,16-tetraenoic acid ethyl ester